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Crystal structure of fenpropathrin.

Kang G, Jeon Y, Lee S, Kim TH - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title compound [systematic name: cyano-(3-phen-oxy-phen-yl)methyl 2,2,3,3-tetra-methyl-cyclo-propane-carboxyl-ate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo-propane ring plane and the carboxyl-ate group plane is 88.25 (11)°.The dihedral angle between the benzene and phenyl rings in the phen-oxy-benzyl group is 82.99 (4)°.In the crystal, C-H⋯N hydrogen bonds and weak C-H⋯π inter-actions link adjacent mol-ecules, forming loop chains along the b-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of Korea.

ABSTRACT
In the title compound [systematic name: cyano-(3-phen-oxy-phen-yl)methyl 2,2,3,3-tetra-methyl-cyclo-propane-carboxyl-ate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo-propane ring plane and the carboxyl-ate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phen-oxy-benzyl group is 82.99 (4)°. In the crystal, C-H⋯N hydrogen bonds and weak C-H⋯π inter-actions link adjacent mol-ecules, forming loop chains along the b-axis direction.

No MeSH data available.


Related in: MedlinePlus

Crystal packing of the title compound with C—H···N hydrogen bonds and weak intermolecular C—H···π interactions are shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity, except H atoms of interactions.
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Fap2: Crystal packing of the title compound with C—H···N hydrogen bonds and weak intermolecular C—H···π interactions are shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity, except H atoms of interactions.


Crystal structure of fenpropathrin.

Kang G, Jeon Y, Lee S, Kim TH - Acta Crystallogr Sect E Struct Rep Online (2014)

Crystal packing of the title compound with C—H···N hydrogen bonds and weak intermolecular C—H···π interactions are shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity, except H atoms of interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257423&req=5

Fap2: Crystal packing of the title compound with C—H···N hydrogen bonds and weak intermolecular C—H···π interactions are shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity, except H atoms of interactions.
Bottom Line: In the title compound [systematic name: cyano-(3-phen-oxy-phen-yl)methyl 2,2,3,3-tetra-methyl-cyclo-propane-carboxyl-ate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo-propane ring plane and the carboxyl-ate group plane is 88.25 (11)°.The dihedral angle between the benzene and phenyl rings in the phen-oxy-benzyl group is 82.99 (4)°.In the crystal, C-H⋯N hydrogen bonds and weak C-H⋯π inter-actions link adjacent mol-ecules, forming loop chains along the b-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of Korea.

ABSTRACT
In the title compound [systematic name: cyano-(3-phen-oxy-phen-yl)methyl 2,2,3,3-tetra-methyl-cyclo-propane-carboxyl-ate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo-propane ring plane and the carboxyl-ate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phen-oxy-benzyl group is 82.99 (4)°. In the crystal, C-H⋯N hydrogen bonds and weak C-H⋯π inter-actions link adjacent mol-ecules, forming loop chains along the b-axis direction.

No MeSH data available.


Related in: MedlinePlus