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About the polymorphism of [Li(C4H8O)3]I: crystal structures of trigonal and tetra-gonal polymorphs.

Gärtner S, Gärtner T, Gschwind RM, Korber N - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the crystal, strands of ion pairs parallel to [001] are observed with an eclipsed conformation of the THF mol-ecules relative to the Li⋯I axis of two adjacent ion pairs.The resulting three-dimensional arrangement shows helical chains of ion pairs parallel to [001].Apart from van der Waals contacts, no remarkable inter-molecular forces are present between the isolated ion pairs in both structures.

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Affiliation: University of Regensburg, Institute of Inorganic Chemistry, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
Two new trigonal and tetra-gonal polymorphs of the title compound, iodido-tris-(tetra-hydro-furan-κO)lithium, are presented, which both include the isolated ion pair Li(THF)3 (+)·I(-). One Li-I ion contact and three tetra-hydro-furan (THF) mol-ecules complete the tetra-hedral coordination of the lithium cation. The three-dimensional arrangement in the two polymorphs differs notably. In the trigonal structure, the ion pair is located on a threefold rotation axis of space group P-3 and only one THF mol-ecule is present in the asymmetric unit. In the crystal, strands of ion pairs parallel to [001] are observed with an eclipsed conformation of the THF mol-ecules relative to the Li⋯I axis of two adjacent ion pairs. In contrast, the tetra-gonal polymorph shows a much larger unit cell in which all atoms are located on general positions of the space group I41 cd. The resulting three-dimensional arrangement shows helical chains of ion pairs parallel to [001]. Apart from van der Waals contacts, no remarkable inter-molecular forces are present between the isolated ion pairs in both structures.

No MeSH data available.


Proposed by NMR in solution: THF addition to iodidocuprates in diethyl ether solutions yields predominantly iodine-free cuprates and solvated Li–I units.
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fig1: Proposed by NMR in solution: THF addition to iodidocuprates in diethyl ether solutions yields predominantly iodine-free cuprates and solvated Li–I units.

Mentions: In our case, we obtained two new polymorphs of [Li(THF)3]+·I− from a solution of (H3C)2CuLi·LiI in diethyl ether covered with THF. The reaction mixture was stored at 193 K, and the measurements for the single-crystal structure analysis were performed at 123 K. The observation of such contact ion pairs directly confirms the NMR spectroscopic findings (Henze et al., 2005 ▶) that upon addition of THF, the LiI units are separated from the cuprate by the coordination of Li+ by three THF mol­ecules (Fig. 1 ▶).


About the polymorphism of [Li(C4H8O)3]I: crystal structures of trigonal and tetra-gonal polymorphs.

Gärtner S, Gärtner T, Gschwind RM, Korber N - Acta Crystallogr Sect E Struct Rep Online (2014)

Proposed by NMR in solution: THF addition to iodidocuprates in diethyl ether solutions yields predominantly iodine-free cuprates and solvated Li–I units.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257418&req=5

fig1: Proposed by NMR in solution: THF addition to iodidocuprates in diethyl ether solutions yields predominantly iodine-free cuprates and solvated Li–I units.
Mentions: In our case, we obtained two new polymorphs of [Li(THF)3]+·I− from a solution of (H3C)2CuLi·LiI in diethyl ether covered with THF. The reaction mixture was stored at 193 K, and the measurements for the single-crystal structure analysis were performed at 123 K. The observation of such contact ion pairs directly confirms the NMR spectroscopic findings (Henze et al., 2005 ▶) that upon addition of THF, the LiI units are separated from the cuprate by the coordination of Li+ by three THF mol­ecules (Fig. 1 ▶).

Bottom Line: In the crystal, strands of ion pairs parallel to [001] are observed with an eclipsed conformation of the THF mol-ecules relative to the Li⋯I axis of two adjacent ion pairs.The resulting three-dimensional arrangement shows helical chains of ion pairs parallel to [001].Apart from van der Waals contacts, no remarkable inter-molecular forces are present between the isolated ion pairs in both structures.

View Article: PubMed Central - HTML - PubMed

Affiliation: University of Regensburg, Institute of Inorganic Chemistry, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
Two new trigonal and tetra-gonal polymorphs of the title compound, iodido-tris-(tetra-hydro-furan-κO)lithium, are presented, which both include the isolated ion pair Li(THF)3 (+)·I(-). One Li-I ion contact and three tetra-hydro-furan (THF) mol-ecules complete the tetra-hedral coordination of the lithium cation. The three-dimensional arrangement in the two polymorphs differs notably. In the trigonal structure, the ion pair is located on a threefold rotation axis of space group P-3 and only one THF mol-ecule is present in the asymmetric unit. In the crystal, strands of ion pairs parallel to [001] are observed with an eclipsed conformation of the THF mol-ecules relative to the Li⋯I axis of two adjacent ion pairs. In contrast, the tetra-gonal polymorph shows a much larger unit cell in which all atoms are located on general positions of the space group I41 cd. The resulting three-dimensional arrangement shows helical chains of ion pairs parallel to [001]. Apart from van der Waals contacts, no remarkable inter-molecular forces are present between the isolated ion pairs in both structures.

No MeSH data available.