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Crystal structure of (2-{3-[4-(4'-cyano-biphenyl-4-yl-oxy)but-oxy]pyridin-2-yl-κN}-5-(dodec-yloxy)phenyl-κC (1))(9-oxo-tetra-cos-7-en-7-olato-κ(2) O,O')platinum(II).

Luo K, Liu H, Guo Q, Luo D - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°.The angle between the planes of the two rings in the biphenyl-4-carbo-nitrile unit is 35.1 (5)°.One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, People's Republic of China.

ABSTRACT
The central Pt(II) atom in the title compound, [Pt(C40H47N2O3)(C24H45O2)], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The angle between the planes of the two rings in the biphenyl-4-carbo-nitrile unit is 35.1 (5)°. One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.

No MeSH data available.


The molecular structure of the title complex, with 50% probability displacement ellipsoids.
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Fap1: The molecular structure of the title complex, with 50% probability displacement ellipsoids.


Crystal structure of (2-{3-[4-(4'-cyano-biphenyl-4-yl-oxy)but-oxy]pyridin-2-yl-κN}-5-(dodec-yloxy)phenyl-κC (1))(9-oxo-tetra-cos-7-en-7-olato-κ(2) O,O')platinum(II).

Luo K, Liu H, Guo Q, Luo D - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of the title complex, with 50% probability displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257408&req=5

Fap1: The molecular structure of the title complex, with 50% probability displacement ellipsoids.
Bottom Line: The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°.The angle between the planes of the two rings in the biphenyl-4-carbo-nitrile unit is 35.1 (5)°.One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, People's Republic of China.

ABSTRACT
The central Pt(II) atom in the title compound, [Pt(C40H47N2O3)(C24H45O2)], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The angle between the planes of the two rings in the biphenyl-4-carbo-nitrile unit is 35.1 (5)°. One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.

No MeSH data available.