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Crystal structure of tin(IV) chloride octa-hydrate.

Hennings E, Schmidt H, Voigt W - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid-liquid phase diagram at lower temperatures.It is built-up of SnCl4(H2O)2 octa-hedral units (point group symmetry 2) and lattice water mol-ecules.An intricate three-dimensional network of O-H⋯O and O-H⋯Cl hydrogen bonds between the complex molecules and the lattice water molecules is formed in the crystal structure.

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Affiliation: TU Bergakademie Freiberg, Institute of Inorganic Chemistry, Leipziger Strasse 29, D-09596 Freiberg, Germany.

ABSTRACT
The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid-liquid phase diagram at lower temperatures. It is built-up of SnCl4(H2O)2 octa-hedral units (point group symmetry 2) and lattice water mol-ecules. An intricate three-dimensional network of O-H⋯O and O-H⋯Cl hydrogen bonds between the complex molecules and the lattice water molecules is formed in the crystal structure.

No MeSH data available.


Formation of chains by water mol­ecules O1 and O2 (bold). Dashed lines indicate hydrogen bonds.
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fig3: Formation of chains by water mol­ecules O1 and O2 (bold). Dashed lines indicate hydrogen bonds.

Mentions: Having a larger view of the crystal structure in direction [001] (Fig. 3 ▶), it becomes obvious that these non-coordinating water mol­ecules form chains between the octa­hedrally coordinated tin(IV) ions. These water mol­ecules (O1 and O2) are connected via hydrogen bonds (Table 1 ▶) and the chains are oriented along the b-axis direction. Considering all types of hydrogen bonding, a three-dimensional network between the complex molecules and the lattice water molecules results.


Crystal structure of tin(IV) chloride octa-hydrate.

Hennings E, Schmidt H, Voigt W - Acta Crystallogr Sect E Struct Rep Online (2014)

Formation of chains by water mol­ecules O1 and O2 (bold). Dashed lines indicate hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257401&req=5

fig3: Formation of chains by water mol­ecules O1 and O2 (bold). Dashed lines indicate hydrogen bonds.
Mentions: Having a larger view of the crystal structure in direction [001] (Fig. 3 ▶), it becomes obvious that these non-coordinating water mol­ecules form chains between the octa­hedrally coordinated tin(IV) ions. These water mol­ecules (O1 and O2) are connected via hydrogen bonds (Table 1 ▶) and the chains are oriented along the b-axis direction. Considering all types of hydrogen bonding, a three-dimensional network between the complex molecules and the lattice water molecules results.

Bottom Line: The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid-liquid phase diagram at lower temperatures.It is built-up of SnCl4(H2O)2 octa-hedral units (point group symmetry 2) and lattice water mol-ecules.An intricate three-dimensional network of O-H⋯O and O-H⋯Cl hydrogen bonds between the complex molecules and the lattice water molecules is formed in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: TU Bergakademie Freiberg, Institute of Inorganic Chemistry, Leipziger Strasse 29, D-09596 Freiberg, Germany.

ABSTRACT
The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid-liquid phase diagram at lower temperatures. It is built-up of SnCl4(H2O)2 octa-hedral units (point group symmetry 2) and lattice water mol-ecules. An intricate three-dimensional network of O-H⋯O and O-H⋯Cl hydrogen bonds between the complex molecules and the lattice water molecules is formed in the crystal structure.

No MeSH data available.