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Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

Mamat C, Flemming A, Köckerling M - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosyl-ated compound.The hy-droxy-methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio.The hy-droxy H atom is not involved in inter-molecular inter-actions, while the hy-droxy O atom serves as a donor for weak C-H⋯O hydrogen bonds, which link the mol-ecules into chains propagating in [0-11].

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Affiliation: Institut für Radiopharmazeutische Krebsforschung, Bautzner Landstr. 400, D-01328 Dresden, Germany.

ABSTRACT
The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosyl-ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)-87.6 (1)°. The hy-droxy-methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hy-droxy H atom is not involved in inter-molecular inter-actions, while the hy-droxy O atom serves as a donor for weak C-H⋯O hydrogen bonds, which link the mol-ecules into chains propagating in [0-11].

No MeSH data available.


A portion of the crystal packing viewed approximately down the a axis. H atoms have been omitted for clarity.
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Fap2: A portion of the crystal packing viewed approximately down the a axis. H atoms have been omitted for clarity.


Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

Mamat C, Flemming A, Köckerling M - Acta Crystallogr Sect E Struct Rep Online (2014)

A portion of the crystal packing viewed approximately down the a axis. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257391&req=5

Fap2: A portion of the crystal packing viewed approximately down the a axis. H atoms have been omitted for clarity.
Bottom Line: The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosyl-ated compound.The hy-droxy-methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio.The hy-droxy H atom is not involved in inter-molecular inter-actions, while the hy-droxy O atom serves as a donor for weak C-H⋯O hydrogen bonds, which link the mol-ecules into chains propagating in [0-11].

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Radiopharmazeutische Krebsforschung, Bautzner Landstr. 400, D-01328 Dresden, Germany.

ABSTRACT
The title compound, C26H21O3P, was obtained as by-product due to the hydrolysis of the desired tosyl-ated compound. The dihedral angles between the three aromatic rings attached to the P atom lie in the range 78.1 (1)-87.6 (1)°. The hy-droxy-methyl group is disordered between two conformations in a 0.719 (9):0.281 (9) ratio. The hy-droxy H atom is not involved in inter-molecular inter-actions, while the hy-droxy O atom serves as a donor for weak C-H⋯O hydrogen bonds, which link the mol-ecules into chains propagating in [0-11].

No MeSH data available.