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Crystal structure of bis-(μ-2,3,4,5-tetra-fluoro-benzoato-κ(2) O:O')bis-[(1,10-phen-anthroline-κ(2) N:N')(2,3,4,5-tetra-fluoro-benzoato-κO)copper(II)] dihydrate.

Sun J - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The basal plane consists of two N atoms [Cu-N = 2.008 (3) and 2.032 (3) Å] from the phenanthroline ligand, and of two carboxyl-ate O atoms [Cu-O = 1.942 (3) and 1.948 (3) Å] from two 2,3,4,5-tetra-fluoro-benzoate anions.Intra-molecular π-π inter-actions between one of the tetra-fluoro-benzene rings and the middle of the phenenanthroline rings [3.617 (3) Å] stabilize the mol-ecular configuration.O-H⋯O hydrogen bonds between the lattice water mol-ecules and the unbound carboxyl-ate O atoms of the metal complexes leads to the formation of a chain structure parallel to [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.

ABSTRACT
In the title compound, [Cu2(C7HF4O2)4(C12H8N2)2]·2H2O, the Cu(II) ion has a square-pyramidal coordination sphere. The basal plane consists of two N atoms [Cu-N = 2.008 (3) and 2.032 (3) Å] from the phenanthroline ligand, and of two carboxyl-ate O atoms [Cu-O = 1.942 (3) and 1.948 (3) Å] from two 2,3,4,5-tetra-fluoro-benzoate anions. Another 2,3,4,5-tetra-fluoro-benzoate anion provides the apical carboxyl-ate O atom [Cu-O = 2.262 (3) Å] and bridges two Cu(II) ions into a binuclear centrosymmetric dimer. Intra-molecular π-π inter-actions between one of the tetra-fluoro-benzene rings and the middle of the phenenanthroline rings [3.617 (3) Å] stabilize the mol-ecular configuration. O-H⋯O hydrogen bonds between the lattice water mol-ecules and the unbound carboxyl-ate O atoms of the metal complexes leads to the formation of a chain structure parallel to [100].

No MeSH data available.


The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. The non-labelled atoms are generated by symmetry code –x + 1, –y + 1, –z + 2.
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Fap1: The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. The non-labelled atoms are generated by symmetry code –x + 1, –y + 1, –z + 2.


Crystal structure of bis-(μ-2,3,4,5-tetra-fluoro-benzoato-κ(2) O:O')bis-[(1,10-phen-anthroline-κ(2) N:N')(2,3,4,5-tetra-fluoro-benzoato-κO)copper(II)] dihydrate.

Sun J - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. The non-labelled atoms are generated by symmetry code –x + 1, –y + 1, –z + 2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257334&req=5

Fap1: The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. The non-labelled atoms are generated by symmetry code –x + 1, –y + 1, –z + 2.
Bottom Line: The basal plane consists of two N atoms [Cu-N = 2.008 (3) and 2.032 (3) Å] from the phenanthroline ligand, and of two carboxyl-ate O atoms [Cu-O = 1.942 (3) and 1.948 (3) Å] from two 2,3,4,5-tetra-fluoro-benzoate anions.Intra-molecular π-π inter-actions between one of the tetra-fluoro-benzene rings and the middle of the phenenanthroline rings [3.617 (3) Å] stabilize the mol-ecular configuration.O-H⋯O hydrogen bonds between the lattice water mol-ecules and the unbound carboxyl-ate O atoms of the metal complexes leads to the formation of a chain structure parallel to [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.

ABSTRACT
In the title compound, [Cu2(C7HF4O2)4(C12H8N2)2]·2H2O, the Cu(II) ion has a square-pyramidal coordination sphere. The basal plane consists of two N atoms [Cu-N = 2.008 (3) and 2.032 (3) Å] from the phenanthroline ligand, and of two carboxyl-ate O atoms [Cu-O = 1.942 (3) and 1.948 (3) Å] from two 2,3,4,5-tetra-fluoro-benzoate anions. Another 2,3,4,5-tetra-fluoro-benzoate anion provides the apical carboxyl-ate O atom [Cu-O = 2.262 (3) Å] and bridges two Cu(II) ions into a binuclear centrosymmetric dimer. Intra-molecular π-π inter-actions between one of the tetra-fluoro-benzene rings and the middle of the phenenanthroline rings [3.617 (3) Å] stabilize the mol-ecular configuration. O-H⋯O hydrogen bonds between the lattice water mol-ecules and the unbound carboxyl-ate O atoms of the metal complexes leads to the formation of a chain structure parallel to [100].

No MeSH data available.