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Crystal structure of (3-carb-oxy-prop-yl)tri-phenyl-phospho-nium hexa-fluorido-phosphate.

Hillesheim PC, Scipione KA, Stokes SL - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title mol-ecular salt, C22H22O2P(+)·PF6 (-), the side chain of the cation adopts an anti-gauche conformation [P-C-C-C and C-C-C-C torsion angles = -179.11 (10) and -77.18 (16)°, respectively].In the crystal, the cations are linked into carb-oxy-lic acid inversion dimers by pairs of O-H⋯O hydrogen bonds.Weak C-H⋯F and C-H⋯(F,F) hydrogen bonds connect the components into a three-dimensional network, but there are no aromatic π-π stacking inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Mississippi State University, Department of Chemistry, 1115 Hand Lab, Box 9573, Mississippi State, MS 39762, USA.

ABSTRACT
In the title mol-ecular salt, C22H22O2P(+)·PF6 (-), the side chain of the cation adopts an anti-gauche conformation [P-C-C-C and C-C-C-C torsion angles = -179.11 (10) and -77.18 (16)°, respectively]. In the crystal, the cations are linked into carb-oxy-lic acid inversion dimers by pairs of O-H⋯O hydrogen bonds. Weak C-H⋯F and C-H⋯(F,F) hydrogen bonds connect the components into a three-dimensional network, but there are no aromatic π-π stacking inter-actions.

No MeSH data available.


Related in: MedlinePlus

Crystal structure and labeling scheme of compound (1). 50% probablility ellipsoids. Phosphorous is in green, oxygen in red, fluorine in purple, and carbon in grey.
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Fap1: Crystal structure and labeling scheme of compound (1). 50% probablility ellipsoids. Phosphorous is in green, oxygen in red, fluorine in purple, and carbon in grey.


Crystal structure of (3-carb-oxy-prop-yl)tri-phenyl-phospho-nium hexa-fluorido-phosphate.

Hillesheim PC, Scipione KA, Stokes SL - Acta Crystallogr Sect E Struct Rep Online (2014)

Crystal structure and labeling scheme of compound (1). 50% probablility ellipsoids. Phosphorous is in green, oxygen in red, fluorine in purple, and carbon in grey.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257321&req=5

Fap1: Crystal structure and labeling scheme of compound (1). 50% probablility ellipsoids. Phosphorous is in green, oxygen in red, fluorine in purple, and carbon in grey.
Bottom Line: In the title mol-ecular salt, C22H22O2P(+)·PF6 (-), the side chain of the cation adopts an anti-gauche conformation [P-C-C-C and C-C-C-C torsion angles = -179.11 (10) and -77.18 (16)°, respectively].In the crystal, the cations are linked into carb-oxy-lic acid inversion dimers by pairs of O-H⋯O hydrogen bonds.Weak C-H⋯F and C-H⋯(F,F) hydrogen bonds connect the components into a three-dimensional network, but there are no aromatic π-π stacking inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Mississippi State University, Department of Chemistry, 1115 Hand Lab, Box 9573, Mississippi State, MS 39762, USA.

ABSTRACT
In the title mol-ecular salt, C22H22O2P(+)·PF6 (-), the side chain of the cation adopts an anti-gauche conformation [P-C-C-C and C-C-C-C torsion angles = -179.11 (10) and -77.18 (16)°, respectively]. In the crystal, the cations are linked into carb-oxy-lic acid inversion dimers by pairs of O-H⋯O hydrogen bonds. Weak C-H⋯F and C-H⋯(F,F) hydrogen bonds connect the components into a three-dimensional network, but there are no aromatic π-π stacking inter-actions.

No MeSH data available.


Related in: MedlinePlus