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Crystal structure of trans-aqua-(perchlorato-κO)bis-(propane-1,3-di-amine-κ(2) N,N')copper(II) perchlorate.

Govindaraj J, Rajkumar K, Ganeshraja AS, Anbalagan K, SubbiahPandi A - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane.The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)].In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).

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Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).

No MeSH data available.


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A view along the a axis of the crystal structure of the title compound. O—H⋯O and N—H⋯O hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; the minor components of the disordered coordinating perchlorate anion and the C-bound H atoms have been omitted for clarity)
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fig2: A view along the a axis of the crystal structure of the title compound. O—H⋯O and N—H⋯O hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; the minor components of the disordered coordinating perchlorate anion and the C-bound H atoms have been omitted for clarity)

Mentions: In the crystal, the various components are linked via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds forming sheets lying parallel to (001); see Table 1 ▶ and Fig. 2 ▶.


Crystal structure of trans-aqua-(perchlorato-κO)bis-(propane-1,3-di-amine-κ(2) N,N')copper(II) perchlorate.

Govindaraj J, Rajkumar K, Ganeshraja AS, Anbalagan K, SubbiahPandi A - Acta Crystallogr Sect E Struct Rep Online (2014)

A view along the a axis of the crystal structure of the title compound. O—H⋯O and N—H⋯O hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; the minor components of the disordered coordinating perchlorate anion and the C-bound H atoms have been omitted for clarity)
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257260&req=5

fig2: A view along the a axis of the crystal structure of the title compound. O—H⋯O and N—H⋯O hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; the minor components of the disordered coordinating perchlorate anion and the C-bound H atoms have been omitted for clarity)
Mentions: In the crystal, the various components are linked via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds forming sheets lying parallel to (001); see Table 1 ▶ and Fig. 2 ▶.

Bottom Line: In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane.The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)].In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).

No MeSH data available.


Related in: MedlinePlus