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Crystal structure of 1-[2,4-bis(4-methoxy-phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone.

Shreevidhyaa Suressh V, Sathya S, Akila A, Ponnuswamy S, Usha G - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The first adopts a chair conformation and the second a half-chair conformation.The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another.The dihedral angle between the planes of the 4-meth-oxy-phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group.

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Affiliation: Department of Physics, Anna Adarsh College for Women, Chennai-40, Tamilnadu, India.

ABSTRACT
In the title compound, C24H29NO3, the aza-bicycle contains two six-membered rings, viz. a cyclo-hexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-meth-oxy-phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, mol-ecules are linked by C-H⋯π inter-actions forming chains along [10-1].

No MeSH data available.


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A view of the crystal packing of the title compound, with C—H···π interactions indicted by dashed lines (see Table 1 for details).
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Fap2: A view of the crystal packing of the title compound, with C—H···π interactions indicted by dashed lines (see Table 1 for details).


Crystal structure of 1-[2,4-bis(4-methoxy-phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone.

Shreevidhyaa Suressh V, Sathya S, Akila A, Ponnuswamy S, Usha G - Acta Crystallogr Sect E Struct Rep Online (2014)

A view of the crystal packing of the title compound, with C—H···π interactions indicted by dashed lines (see Table 1 for details).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257259&req=5

Fap2: A view of the crystal packing of the title compound, with C—H···π interactions indicted by dashed lines (see Table 1 for details).
Bottom Line: The first adopts a chair conformation and the second a half-chair conformation.The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another.The dihedral angle between the planes of the 4-meth-oxy-phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Anna Adarsh College for Women, Chennai-40, Tamilnadu, India.

ABSTRACT
In the title compound, C24H29NO3, the aza-bicycle contains two six-membered rings, viz. a cyclo-hexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-meth-oxy-phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, mol-ecules are linked by C-H⋯π inter-actions forming chains along [10-1].

No MeSH data available.


Related in: MedlinePlus