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Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate.

Yoshinari N, Konno T - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The dihedral angles between the planes of the rings in the organic mol-ecules are 86.84 (10) and 88.77 (11)°.An intramolecular N-H⋯S hydrogen bond occurs.In the crystal, organic and water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a tape structure running along the b-axis direction.

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Affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

ABSTRACT
In the asymmetric unit of the title compound, C19H23NO2S·H2O, there are two independent organic mol-ecules and two water mol-ecules. Both organic mol-ecules exist as the zwitterionic form. The dihedral angles between the planes of the rings in the organic mol-ecules are 86.84 (10) and 88.77 (11)°. An intramolecular N-H⋯S hydrogen bond occurs. In the crystal, organic and water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a tape structure running along the b-axis direction.

No MeSH data available.


A view of the tape structure running along the b axis in (I). Blue dashed lines indicate hydrogen bonds. [Symmetry codes: (i) x, y + 1, z; (ii) x, y–1, z.]
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Fap2: A view of the tape structure running along the b axis in (I). Blue dashed lines indicate hydrogen bonds. [Symmetry codes: (i) x, y + 1, z; (ii) x, y–1, z.]


Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate.

Yoshinari N, Konno T - Acta Crystallogr Sect E Struct Rep Online (2014)

A view of the tape structure running along the b axis in (I). Blue dashed lines indicate hydrogen bonds. [Symmetry codes: (i) x, y + 1, z; (ii) x, y–1, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
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getmorefigures.php?uid=PMC4257258&req=5

Fap2: A view of the tape structure running along the b axis in (I). Blue dashed lines indicate hydrogen bonds. [Symmetry codes: (i) x, y + 1, z; (ii) x, y–1, z.]
Bottom Line: The dihedral angles between the planes of the rings in the organic mol-ecules are 86.84 (10) and 88.77 (11)°.An intramolecular N-H⋯S hydrogen bond occurs.In the crystal, organic and water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a tape structure running along the b-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

ABSTRACT
In the asymmetric unit of the title compound, C19H23NO2S·H2O, there are two independent organic mol-ecules and two water mol-ecules. Both organic mol-ecules exist as the zwitterionic form. The dihedral angles between the planes of the rings in the organic mol-ecules are 86.84 (10) and 88.77 (11)°. An intramolecular N-H⋯S hydrogen bond occurs. In the crystal, organic and water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a tape structure running along the b-axis direction.

No MeSH data available.