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Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa-hydro-4,7-methano-2-benzo-thio-phene 2,2-dioxide.

Kotha S, Gunta R - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound C15H20O2S, was identified as a product of di-allyl-ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound.The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131).Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.

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Affiliation: Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai 400 076, India.

ABSTRACT
The title compound C15H20O2S, was identified as a product of di-allyl-ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131). Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.

No MeSH data available.


The stucture of the title compound showing labeling of non-H atoms.
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Fap1: The stucture of the title compound showing labeling of non-H atoms.


Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa-hydro-4,7-methano-2-benzo-thio-phene 2,2-dioxide.

Kotha S, Gunta R - Acta Crystallogr Sect E Struct Rep Online (2014)

The stucture of the title compound showing labeling of non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257250&req=5

Fap1: The stucture of the title compound showing labeling of non-H atoms.
Bottom Line: The title compound C15H20O2S, was identified as a product of di-allyl-ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound.The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131).Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai 400 076, India.

ABSTRACT
The title compound C15H20O2S, was identified as a product of di-allyl-ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131). Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.

No MeSH data available.