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Crystal structure of bromido-bis-(naph-thal-en-1-yl)anti-mony(III).

Shawkataly OB, Hussien Abdelnasir HM, Rosli MM - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°.An intra-molecular C-H⋯Br hydrogen bond forms an S(5) ring motif.In the crystal, weak C-H⋯Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

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Affiliation: Chemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

ABSTRACT
In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra-molecular C-H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C-H⋯Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

No MeSH data available.


The molecular structure of the title compound, showing 50% probability displacement ellipsoids. The dashed line indicates the C—H···Br hydrogen bond.
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Fap1: The molecular structure of the title compound, showing 50% probability displacement ellipsoids. The dashed line indicates the C—H···Br hydrogen bond.


Crystal structure of bromido-bis-(naph-thal-en-1-yl)anti-mony(III).

Shawkataly OB, Hussien Abdelnasir HM, Rosli MM - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of the title compound, showing 50% probability displacement ellipsoids. The dashed line indicates the C—H···Br hydrogen bond.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257233&req=5

Fap1: The molecular structure of the title compound, showing 50% probability displacement ellipsoids. The dashed line indicates the C—H···Br hydrogen bond.
Bottom Line: In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°.An intra-molecular C-H⋯Br hydrogen bond forms an S(5) ring motif.In the crystal, weak C-H⋯Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

ABSTRACT
In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra-molecular C-H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C-H⋯Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

No MeSH data available.