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Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III).

Wang L, Yang L - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, [Al(CH3)2(C30H41O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH3)3 in a nitro-gen atmosphere.In the mol-ecule, the coordination geometry around the Al(III) atom is slightly distorted C2O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds.The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, People's Republic of China.

ABSTRACT
The title compound, [Al(CH3)2(C30H41O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH3)3 in a nitro-gen atmosphere. In the mol-ecule, the coordination geometry around the Al(III) atom is slightly distorted C2O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds. The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°]. There is no inter-molecular hydrogen bonding in the crystal structure.

No MeSH data available.


An ORTEP view of the molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at 30%. The H atoms have been omitted for clarity.
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Fap1: An ORTEP view of the molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at 30%. The H atoms have been omitted for clarity.


Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III).

Wang L, Yang L - Acta Crystallogr Sect E Struct Rep Online (2014)

An ORTEP view of the molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at 30%. The H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257224&req=5

Fap1: An ORTEP view of the molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at 30%. The H atoms have been omitted for clarity.
Bottom Line: The title compound, [Al(CH3)2(C30H41O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH3)3 in a nitro-gen atmosphere.In the mol-ecule, the coordination geometry around the Al(III) atom is slightly distorted C2O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds.The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, People's Republic of China.

ABSTRACT
The title compound, [Al(CH3)2(C30H41O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH3)3 in a nitro-gen atmosphere. In the mol-ecule, the coordination geometry around the Al(III) atom is slightly distorted C2O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds. The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°]. There is no inter-molecular hydrogen bonding in the crystal structure.

No MeSH data available.