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Advances in the chemistry of oxaziridines.
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PubMed Central - PubMed
Affiliation: Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.
reagents; oxidations and aminations of alkanes, alkenes, arenes, amines, identity of their N-substituent, which exerts a significant effect on their reactivity... and acid, only the tert-butyldiphenylsilyl (TBDPS) derivative has been successfully synthesized... in oxygen transfer reactions to alkenes... tend to be more powerful oxygen atom-transfer reagents, these positively asymmetric epoxidation reactions with moderate to excellent enantioselectivities the α-alcohol after ring-opening of the epoxide... Directed reduction for decomposition of the oxaziridine... Thus, one-electron reduction invoked in Scheme 28... The greater reactivity oxygen atom transfer reactions continues to be the most broadly appreciated |
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sch26: Complementary Dipole Formation from N-Sulfonyloxaziridines |
View Article: PubMed Central - PubMed
Affiliation: Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.
reagents; oxidations and aminations of alkanes, alkenes, arenes, amines, identity of their N-substituent, which exerts a significant effect on their reactivity... and acid, only the tert-butyldiphenylsilyl (TBDPS) derivative has been successfully synthesized... in oxygen transfer reactions to alkenes... tend to be more powerful oxygen atom-transfer reagents, these positively asymmetric epoxidation reactions with moderate to excellent enantioselectivities the α-alcohol after ring-opening of the epoxide... Directed reduction for decomposition of the oxaziridine... Thus, one-electron reduction invoked in Scheme 28... The greater reactivity oxygen atom transfer reactions continues to be the most broadly appreciated
