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Advances in the chemistry of oxaziridines.

Williamson KS, Michaelis DJ, Yoon TP - Chem. Rev. (2014)

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Affiliation: Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.

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reagents; oxidations and aminations of alkanes, alkenes, arenes, amines, identity of their N-substituent, which exerts a significant effect on their reactivity... and acid, only the tert-butyldiphenylsilyl (TBDPS) derivative has been successfully synthesized... in oxygen transfer reactions to alkenes... tend to be more powerful oxygen atom-transfer reagents, these positively asymmetric epoxidation reactions with moderate to excellent enantioselectivities the α-alcohol after ring-opening of the epoxide... Directed reduction for decomposition of the oxaziridine... Thus, one-electron reduction invoked in Scheme 28... The greater reactivity oxygen atom transfer reactions continues to be the most broadly appreciated

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Catalytic EnantioselectiveRoutes to Chiral Oxaziridines
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sch8: Catalytic EnantioselectiveRoutes to Chiral Oxaziridines


Advances in the chemistry of oxaziridines.

Williamson KS, Michaelis DJ, Yoon TP - Chem. Rev. (2014)

Catalytic EnantioselectiveRoutes to Chiral Oxaziridines
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Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4150611&req=5

sch8: Catalytic EnantioselectiveRoutes to Chiral Oxaziridines

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

reagents; oxidations and aminations of alkanes, alkenes, arenes, amines, identity of their N-substituent, which exerts a significant effect on their reactivity... and acid, only the tert-butyldiphenylsilyl (TBDPS) derivative has been successfully synthesized... in oxygen transfer reactions to alkenes... tend to be more powerful oxygen atom-transfer reagents, these positively asymmetric epoxidation reactions with moderate to excellent enantioselectivities the α-alcohol after ring-opening of the epoxide... Directed reduction for decomposition of the oxaziridine... Thus, one-electron reduction invoked in Scheme 28... The greater reactivity oxygen atom transfer reactions continues to be the most broadly appreciated

Show MeSH