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Tetra-amminepalladium(II) dichloride ammonia tetra-solvate.

Grassl T, Korber N - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The chloride anions are surrounded by nine ammonia mol-ecules.These are either bound in the palladium complex or solvent mol-ecules.The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.

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Affiliation: Institut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.

No MeSH data available.


: Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: (i) 1 - x, 1 - y, - z.
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Fap1: : Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: (i) 1 - x, 1 - y, - z.


Tetra-amminepalladium(II) dichloride ammonia tetra-solvate.

Grassl T, Korber N - Acta Crystallogr Sect E Struct Rep Online (2014)

: Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: (i) 1 - x, 1 - y, - z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120636&req=5

Fap1: : Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: (i) 1 - x, 1 - y, - z.
Bottom Line: The chloride anions are surrounded by nine ammonia mol-ecules.These are either bound in the palladium complex or solvent mol-ecules.The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.

No MeSH data available.