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catena-Poly[[bis-(dicyanamido-κN (1))cobalt(II)]bis-{μ-1,2-bis-[(1,2,4-triazol-1-yl)meth-yl]benzene-κ(2) N (4):N (4')}].

Zhang J, Shen X - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title complex, [Co(C2N3)2(C12H12N6)2] n the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octa-hedral coordination geometry.The dihedral angles formed by the planes of the triazole rings with those of the benzene ring are 79.4 (2) and 79.1 (2)°.In the crystal, the chains inter-act through C-H⋯N hydrogen bonds, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title complex, [Co(C2N3)2(C12H12N6)2] n the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octa-hedral coordination geometry. The 1,2-bis-[(1,2,4-triazol-1-yl)meth-yl]benzene ligands link adjacent metal atoms into polymeric chains parallel to the c axis, forming centrosymmetric 26-membered metallamacrocycles. The conformation of the metallamacrocycles is stabilized by pairs of C-H⋯N hydrogen bonds. The dihedral angles formed by the planes of the triazole rings with those of the benzene ring are 79.4 (2) and 79.1 (2)°. In the crystal, the chains inter-act through C-H⋯N hydrogen bonds, forming a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level. Symmetry codes: (i) -x + 2, -y, -z; (ii) -x + 2, -y, -z + 1; (iii) x, y, z - 1]. Hydrogen atoms are omitted for clarity.
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Fap1: The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level. Symmetry codes: (i) -x + 2, -y, -z; (ii) -x + 2, -y, -z + 1; (iii) x, y, z - 1]. Hydrogen atoms are omitted for clarity.


catena-Poly[[bis-(dicyanamido-κN (1))cobalt(II)]bis-{μ-1,2-bis-[(1,2,4-triazol-1-yl)meth-yl]benzene-κ(2) N (4):N (4')}].

Zhang J, Shen X - Acta Crystallogr Sect E Struct Rep Online (2014)

The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level. Symmetry codes: (i) -x + 2, -y, -z; (ii) -x + 2, -y, -z + 1; (iii) x, y, z - 1]. Hydrogen atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120635&req=5

Fap1: The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level. Symmetry codes: (i) -x + 2, -y, -z; (ii) -x + 2, -y, -z + 1; (iii) x, y, z - 1]. Hydrogen atoms are omitted for clarity.
Bottom Line: In the title complex, [Co(C2N3)2(C12H12N6)2] n the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octa-hedral coordination geometry.The dihedral angles formed by the planes of the triazole rings with those of the benzene ring are 79.4 (2) and 79.1 (2)°.In the crystal, the chains inter-act through C-H⋯N hydrogen bonds, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title complex, [Co(C2N3)2(C12H12N6)2] n the Co(II) atom lies on a centre of symmetry and displays a slightly distorted octa-hedral coordination geometry. The 1,2-bis-[(1,2,4-triazol-1-yl)meth-yl]benzene ligands link adjacent metal atoms into polymeric chains parallel to the c axis, forming centrosymmetric 26-membered metallamacrocycles. The conformation of the metallamacrocycles is stabilized by pairs of C-H⋯N hydrogen bonds. The dihedral angles formed by the planes of the triazole rings with those of the benzene ring are 79.4 (2) and 79.1 (2)°. In the crystal, the chains inter-act through C-H⋯N hydrogen bonds, forming a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus