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Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di-hydro-pyridine-3,5-di-carboxyl-ate.

Steiger SA, Monacelli AJ, Li C, Hunting JL, Natale NR - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, C25H27NO4, has a flattened di-hydro-pyridine ring.The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di-hydro-pyridine ring.Intra-molecular C-H⋯O hydrogen bonds are also observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biomedical and Pharmaceutical Sciences, The University of Montana, 32 Campus Drive, Missoula, MT 59812, USA.

ABSTRACT
The title compound, C25H27NO4, has a flattened di-hydro-pyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di-hydro-pyridine ring. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O inter-actions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intra-molecular C-H⋯O hydrogen bonds are also observed.

No MeSH data available.


Related in: MedlinePlus

Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level.
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Fap1: Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level.


Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-di-hydro-pyridine-3,5-di-carboxyl-ate.

Steiger SA, Monacelli AJ, Li C, Hunting JL, Natale NR - Acta Crystallogr Sect E Struct Rep Online (2014)

Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120632&req=5

Fap1: Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The title compound, C25H27NO4, has a flattened di-hydro-pyridine ring.The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di-hydro-pyridine ring.Intra-molecular C-H⋯O hydrogen bonds are also observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biomedical and Pharmaceutical Sciences, The University of Montana, 32 Campus Drive, Missoula, MT 59812, USA.

ABSTRACT
The title compound, C25H27NO4, has a flattened di-hydro-pyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)°; the axis of the biphenyl rings makes an 81.05 (9)° angle to the plane of the di-hydro-pyridine ring. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O inter-actions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intra-molecular C-H⋯O hydrogen bonds are also observed.

No MeSH data available.


Related in: MedlinePlus