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Dimanganese(II) hydroxide vanadate, Mn2(OH)[VO4].

Sun K, Möller A - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: These polyhedra are linked through common edges, forming a corrugated layer-type of structure extending parallel to (100).A three-dimensional framework results via additional Mn-O-V-O-Mn connectivities involving the two different tetra-hedral [VO4] units (each with point-group symmetry .m.).O-H⋯O hydrogen bonds (one bifurcated) between the OH functions (both with point-group symmetry .m.) and the [VO4] units complete this arrangement.

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Affiliation: 112 Fleming Building, Department of Chemistry, University of Houston, Houston, TX 77204-5003, USA.

ABSTRACT
Dimanganese(II) hydroxide vanadate was obtained from hydro-thermal reactions. The crystal structure of the title compound is isotypic with that of Zn2(OH)[VO4]. Three crystallographically independent Mn(2+) ions are present, one (site symmetry .m.) with a distorted trigonal-bipyramidal and two (site symmetries .m. and 1) with distorted octa-hedral coordination spheres. These polyhedra are linked through common edges, forming a corrugated layer-type of structure extending parallel to (100). A three-dimensional framework results via additional Mn-O-V-O-Mn connectivities involving the two different tetra-hedral [VO4] units (each with point-group symmetry .m.). O-H⋯O hydrogen bonds (one bifurcated) between the OH functions (both with point-group symmetry .m.) and the [VO4] units complete this arrangement.

No MeSH data available.


A projection of the crystal structure of Mn2(OH)[VO4] along [011]. Displacement ellipsoids are drawn at the 75% probability level.
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Fap1: A projection of the crystal structure of Mn2(OH)[VO4] along [011]. Displacement ellipsoids are drawn at the 75% probability level.


Dimanganese(II) hydroxide vanadate, Mn2(OH)[VO4].

Sun K, Möller A - Acta Crystallogr Sect E Struct Rep Online (2014)

A projection of the crystal structure of Mn2(OH)[VO4] along [011]. Displacement ellipsoids are drawn at the 75% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120627&req=5

Fap1: A projection of the crystal structure of Mn2(OH)[VO4] along [011]. Displacement ellipsoids are drawn at the 75% probability level.
Bottom Line: These polyhedra are linked through common edges, forming a corrugated layer-type of structure extending parallel to (100).A three-dimensional framework results via additional Mn-O-V-O-Mn connectivities involving the two different tetra-hedral [VO4] units (each with point-group symmetry .m.).O-H⋯O hydrogen bonds (one bifurcated) between the OH functions (both with point-group symmetry .m.) and the [VO4] units complete this arrangement.

View Article: PubMed Central - HTML - PubMed

Affiliation: 112 Fleming Building, Department of Chemistry, University of Houston, Houston, TX 77204-5003, USA.

ABSTRACT
Dimanganese(II) hydroxide vanadate was obtained from hydro-thermal reactions. The crystal structure of the title compound is isotypic with that of Zn2(OH)[VO4]. Three crystallographically independent Mn(2+) ions are present, one (site symmetry .m.) with a distorted trigonal-bipyramidal and two (site symmetries .m. and 1) with distorted octa-hedral coordination spheres. These polyhedra are linked through common edges, forming a corrugated layer-type of structure extending parallel to (100). A three-dimensional framework results via additional Mn-O-V-O-Mn connectivities involving the two different tetra-hedral [VO4] units (each with point-group symmetry .m.). O-H⋯O hydrogen bonds (one bifurcated) between the OH functions (both with point-group symmetry .m.) and the [VO4] units complete this arrangement.

No MeSH data available.