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2,3,5,6-Tetra-fluoro-1,4-bis-({[(thio-phen-2-yl)methyl-idene]amino}-meth-yl)benzene.

Gao N, Luo HK, Qin RR, He MY - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title compound, C18H12F4N2S2, a bis-thio-phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry.The thio-phene and tetra-fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°.The crystal structure exhibits C-H⋯F hydrogen bonds, resulting in supra-molecular chains along the c-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People's Republic of China.

ABSTRACT
In the title compound, C18H12F4N2S2, a bis-thio-phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry. The thio-phene and tetra-fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°. The crystal structure exhibits C-H⋯F hydrogen bonds, resulting in supra-molecular chains along the c-axis direction.

No MeSH data available.


View of the one-dimensional supramolecular chain structure constructed via intermolecular C—H···F hydrogen-bonding interactions (irrelative hydrogen atoms are omitted for clarity).
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Fap2: View of the one-dimensional supramolecular chain structure constructed via intermolecular C—H···F hydrogen-bonding interactions (irrelative hydrogen atoms are omitted for clarity).


2,3,5,6-Tetra-fluoro-1,4-bis-({[(thio-phen-2-yl)methyl-idene]amino}-meth-yl)benzene.

Gao N, Luo HK, Qin RR, He MY - Acta Crystallogr Sect E Struct Rep Online (2014)

View of the one-dimensional supramolecular chain structure constructed via intermolecular C—H···F hydrogen-bonding interactions (irrelative hydrogen atoms are omitted for clarity).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120615&req=5

Fap2: View of the one-dimensional supramolecular chain structure constructed via intermolecular C—H···F hydrogen-bonding interactions (irrelative hydrogen atoms are omitted for clarity).
Bottom Line: In the title compound, C18H12F4N2S2, a bis-thio-phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry.The thio-phene and tetra-fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°.The crystal structure exhibits C-H⋯F hydrogen bonds, resulting in supra-molecular chains along the c-axis direction.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Petrochemical Engineering, Changzhou University, Changzhou 213164, People's Republic of China.

ABSTRACT
In the title compound, C18H12F4N2S2, a bis-thio-phenyl Schiff base ligand with a perifluorinated aromatic core, the complete molecule is generated by crystallographic inversion symmetry. The thio-phene and tetra-fluorinated benzene rings are oriented at a dihedral angle of 77.38 (4)°. The crystal structure exhibits C-H⋯F hydrogen bonds, resulting in supra-molecular chains along the c-axis direction.

No MeSH data available.