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(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Mekarat S, Pakawatchai C, Saithong S - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms.In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops.The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.

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Affiliation: Faculty of Science and Technology, Princess of Naradhiwas University, Narathiwat, 96000, Thailand.

ABSTRACT
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of [Ag(ptu)(PPh3)2]NO3 complex. Displacement ellipsoids are shown at 50% probability level.
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Fap1: The molecular structure of [Ag(ptu)(PPh3)2]NO3 complex. Displacement ellipsoids are shown at 50% probability level.


(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Mekarat S, Pakawatchai C, Saithong S - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of [Ag(ptu)(PPh3)2]NO3 complex. Displacement ellipsoids are shown at 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120613&req=5

Fap1: The molecular structure of [Ag(ptu)(PPh3)2]NO3 complex. Displacement ellipsoids are shown at 50% probability level.
Bottom Line: In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms.In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops.The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Science and Technology, Princess of Naradhiwas University, Narathiwat, 96000, Thailand.

ABSTRACT
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus