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catena-Poly[[trans-bis-(1,3-benzo-thia-zole-κN)manganese(II)]-di-μ-chlorido].

Bouchareb H, Benmebarek S, Bouacida S, Merazig H, Boudraa M - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites.The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis.The crystal packing can be descibed as alternating layers parallel to (001) featuring π-π stacking inter-actions with a centroid-centroid distance of 3.6029 (15) Å.

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Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000, Algeria.

ABSTRACT
In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π-π stacking inter-actions with a centroid-centroid distance of 3.6029 (15) Å.

No MeSH data available.


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The coordination around the MnII ion in a chain of octahedra parallel to the c axis
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Fap2: The coordination around the MnII ion in a chain of octahedra parallel to the c axis


catena-Poly[[trans-bis-(1,3-benzo-thia-zole-κN)manganese(II)]-di-μ-chlorido].

Bouchareb H, Benmebarek S, Bouacida S, Merazig H, Boudraa M - Acta Crystallogr Sect E Struct Rep Online (2014)

The coordination around the MnII ion in a chain of octahedra parallel to the c axis
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120608&req=5

Fap2: The coordination around the MnII ion in a chain of octahedra parallel to the c axis
Bottom Line: In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites.The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis.The crystal packing can be descibed as alternating layers parallel to (001) featuring π-π stacking inter-actions with a centroid-centroid distance of 3.6029 (15) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000, Algeria.

ABSTRACT
In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π-π stacking inter-actions with a centroid-centroid distance of 3.6029 (15) Å.

No MeSH data available.


Related in: MedlinePlus