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(η(6)-Benzene)(carbonato-κ(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-κP]ruthenium(II) chloro-form tris-olvate.

Gowrisankar S, Neumann H, Spannenberg A, Beller M - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶).Acta Cryst.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: Division of Organic Chemistry, Institute of Chemical and Engineering Sciences, 8 Biomedical grove, Neuros, #07-01, 138665, Singapore.

ABSTRACT
The title compound, [Ru(CO3)(η(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(η(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The asymmetric unit contains one metal complex and three chloro-form solvent mol-ecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with atoms at the 30% probability level for the displacement ellipsoids. Hydrogen atoms are omitted for clarity.
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Fap1: The molecular structure of the title compound with atoms at the 30% probability level for the displacement ellipsoids. Hydrogen atoms are omitted for clarity.


(η(6)-Benzene)(carbonato-κ(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-κP]ruthenium(II) chloro-form tris-olvate.

Gowrisankar S, Neumann H, Spannenberg A, Beller M - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of the title compound with atoms at the 30% probability level for the displacement ellipsoids. Hydrogen atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120604&req=5

Fap1: The molecular structure of the title compound with atoms at the 30% probability level for the displacement ellipsoids. Hydrogen atoms are omitted for clarity.
Bottom Line: The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶).Acta Cryst.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: Division of Organic Chemistry, Institute of Chemical and Engineering Sciences, 8 Biomedical grove, Neuros, #07-01, 138665, Singapore.

ABSTRACT
The title compound, [Ru(CO3)(η(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(η(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The asymmetric unit contains one metal complex and three chloro-form solvent mol-ecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].

No MeSH data available.


Related in: MedlinePlus