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fac-[1,2-Bis(pyridin-4-yl)ethane-κN]tricarbon-yl(1,10-phenanthroline-κ(2) N,N')rhenium(I) hexa-fluorido-phosphate aceto-nitrile monosolvate.

Guilardi S, Patrocinio AO, de Sousa SF, Ellena J - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The asymmetric unit of the title compound, [Re(C12H8N2)(C12H12N2)(CO)3]PF6.·CH3CN, contains one cation, one hexa-fluorido-phosphate anion and one aceto-nitrile solvent mol-ecule.The Re(I) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis-(pyridin-4-yl)ethane ligand [mean Re-N = 2.191 (15) Å] and by three carbonyl ligands [mean Re-C = 1.926 (3) Å] in a distorted octa-hedral geometry.The crystal packing exhibits short inter-molecular O⋯O distance of 2.795 (5) Å between two cations related by inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Instituto de Química - UFU, Uberlândia-MG, Brazil.

ABSTRACT
The asymmetric unit of the title compound, [Re(C12H8N2)(C12H12N2)(CO)3]PF6.·CH3CN, contains one cation, one hexa-fluorido-phosphate anion and one aceto-nitrile solvent mol-ecule. The Re(I) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis-(pyridin-4-yl)ethane ligand [mean Re-N = 2.191 (15) Å] and by three carbonyl ligands [mean Re-C = 1.926 (3) Å] in a distorted octa-hedral geometry. The electrostatic forces and weak C-H⋯F(O) hydrogen bonds pack cations and anions into the crystal with voids of 82 Å(3), which are filled by solvent mol-ecules. The crystal packing exhibits short inter-molecular O⋯O distance of 2.795 (5) Å between two cations related by inversion.

No MeSH data available.


A view of the asymmetric unit of the title compound, showing the atom labeling and 30% probability displacement ellipsoids.
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Fap1: A view of the asymmetric unit of the title compound, showing the atom labeling and 30% probability displacement ellipsoids.


fac-[1,2-Bis(pyridin-4-yl)ethane-κN]tricarbon-yl(1,10-phenanthroline-κ(2) N,N')rhenium(I) hexa-fluorido-phosphate aceto-nitrile monosolvate.

Guilardi S, Patrocinio AO, de Sousa SF, Ellena J - Acta Crystallogr Sect E Struct Rep Online (2014)

A view of the asymmetric unit of the title compound, showing the atom labeling and 30% probability displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120603&req=5

Fap1: A view of the asymmetric unit of the title compound, showing the atom labeling and 30% probability displacement ellipsoids.
Bottom Line: The asymmetric unit of the title compound, [Re(C12H8N2)(C12H12N2)(CO)3]PF6.·CH3CN, contains one cation, one hexa-fluorido-phosphate anion and one aceto-nitrile solvent mol-ecule.The Re(I) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis-(pyridin-4-yl)ethane ligand [mean Re-N = 2.191 (15) Å] and by three carbonyl ligands [mean Re-C = 1.926 (3) Å] in a distorted octa-hedral geometry.The crystal packing exhibits short inter-molecular O⋯O distance of 2.795 (5) Å between two cations related by inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Instituto de Química - UFU, Uberlândia-MG, Brazil.

ABSTRACT
The asymmetric unit of the title compound, [Re(C12H8N2)(C12H12N2)(CO)3]PF6.·CH3CN, contains one cation, one hexa-fluorido-phosphate anion and one aceto-nitrile solvent mol-ecule. The Re(I) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis-(pyridin-4-yl)ethane ligand [mean Re-N = 2.191 (15) Å] and by three carbonyl ligands [mean Re-C = 1.926 (3) Å] in a distorted octa-hedral geometry. The electrostatic forces and weak C-H⋯F(O) hydrogen bonds pack cations and anions into the crystal with voids of 82 Å(3), which are filled by solvent mol-ecules. The crystal packing exhibits short inter-molecular O⋯O distance of 2.795 (5) Å between two cations related by inversion.

No MeSH data available.