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(5-n-Butyl-10,20-diiso-butyl-porphyrin-ato)nickel(II).

Senge MO, Dahms K - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules.The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other.The compound was prepared via nucleophilic substitution of (5,15-diiso-butyl-porphyrinato)nickel(II) with n-butyl-lithium.

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Affiliation: SFI Tetrapyrrole Laboratory, School of Chemistry, Trinity College Dublin, Dublin 2, Ireland.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent mol-ecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules. The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other. The compound was prepared via nucleophilic substitution of (5,15-diiso-butyl-porphyrinato)nickel(II) with n-butyl-lithium.

No MeSH data available.


Related in: MedlinePlus

View of the molecular arrangement of (II) in the crystal. Dashed lines indicate short Ni···H separations.
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Fap4: View of the molecular arrangement of (II) in the crystal. Dashed lines indicate short Ni···H separations.


(5-n-Butyl-10,20-diiso-butyl-porphyrin-ato)nickel(II).

Senge MO, Dahms K - Acta Crystallogr Sect E Struct Rep Online (2014)

View of the molecular arrangement of (II) in the crystal. Dashed lines indicate short Ni···H separations.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120589&req=5

Fap4: View of the molecular arrangement of (II) in the crystal. Dashed lines indicate short Ni···H separations.
Bottom Line: The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules.The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other.The compound was prepared via nucleophilic substitution of (5,15-diiso-butyl-porphyrinato)nickel(II) with n-butyl-lithium.

View Article: PubMed Central - HTML - PubMed

Affiliation: SFI Tetrapyrrole Laboratory, School of Chemistry, Trinity College Dublin, Dublin 2, Ireland.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent mol-ecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules. The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other. The compound was prepared via nucleophilic substitution of (5,15-diiso-butyl-porphyrinato)nickel(II) with n-butyl-lithium.

No MeSH data available.


Related in: MedlinePlus