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Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen-oxy-phen-yl)thio-urea.

Jeon Y, Kang G, Cho S, Kim TH - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, C23H32N2OS, is a thio-urea-based insecticide.The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio-urea group and the diisopropyl benzene ring is 86.00 (5)°.Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of Korea.

ABSTRACT
The title compound, C23H32N2OS, is a thio-urea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio-urea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N-H⋯S hydrogen bonds link adjacent mol-ecules, forming R 2 (2)(8) inversion dimers that pack into chains along the b-axis direction.

No MeSH data available.


Crystal packing of the title compound with N—H···S hydrogen bonds shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity. Only atoms of the major disorder components are shown.
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Fap2: Crystal packing of the title compound with N—H···S hydrogen bonds shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity. Only atoms of the major disorder components are shown.


Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen-oxy-phen-yl)thio-urea.

Jeon Y, Kang G, Cho S, Kim TH - Acta Crystallogr Sect E Struct Rep Online (2014)

Crystal packing of the title compound with N—H···S hydrogen bonds shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity. Only atoms of the major disorder components are shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120544&req=5

Fap2: Crystal packing of the title compound with N—H···S hydrogen bonds shown as dashed lines. H atoms bonded to C atoms have been omitted for clarity. Only atoms of the major disorder components are shown.
Bottom Line: The title compound, C23H32N2OS, is a thio-urea-based insecticide.The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio-urea group and the diisopropyl benzene ring is 86.00 (5)°.Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of Korea.

ABSTRACT
The title compound, C23H32N2OS, is a thio-urea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio-urea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N-H⋯S hydrogen bonds link adjacent mol-ecules, forming R 2 (2)(8) inversion dimers that pack into chains along the b-axis direction.

No MeSH data available.