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Crystal structure of chlorido-(piperidine-κN)(quinoline-2-carboxyl-ato-κ(2) N,O)platinum(II).

Nguyen Thi Thanh C, Nguyen Bich N, Van Meervelt L - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, [Pt(C10H6NO2)Cl(C5H11N)], crystallizes with one mol-ecule in the asymmetric unit.The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxyl-ate O atom of the bidentate quinaldate ligand and a piperidine N atom.In the crystal, mol-ecules are stacked into columns along the c axis by the formation of N-H⋯Cl and C-H⋯O hydrogen bonds.

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Affiliation: Chemistry Department, Hanoi National University of Education, 136 - Xuan Thuy - Cau Giay, Hanoi, Vietnam.

ABSTRACT
The title compound, [Pt(C10H6NO2)Cl(C5H11N)], crystallizes with one mol-ecule in the asymmetric unit. The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxyl-ate O atom of the bidentate quinaldate ligand and a piperidine N atom. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, mol-ecules are stacked into columns along the c axis by the formation of N-H⋯Cl and C-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

View of the crystal packing for the title compound, with (N/C)—H⋯Cl and C—H⋯O hydrogen bonds drawn as green and red dashed lines, respectively. [Symmetry codes: (i) x, −y + 1, z − ; (ii) −x + 1, y, −z + .]
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fig2: View of the crystal packing for the title compound, with (N/C)—H⋯Cl and C—H⋯O hydrogen bonds drawn as green and red dashed lines, respectively. [Symmetry codes: (i) x, −y + 1, z − ; (ii) −x + 1, y, −z + .]

Mentions: The crystal packing is characterized by N—H⋯Cl and C—H⋯O hydrogen bonds (Table 1 ▶). Mol­ecules are arranged into columns along the c axis (Fig. 2 ▶) with the piperidine rings all directed towards the center of the column, favouring hydro­phobic inter­actions.


Crystal structure of chlorido-(piperidine-κN)(quinoline-2-carboxyl-ato-κ(2) N,O)platinum(II).

Nguyen Thi Thanh C, Nguyen Bich N, Van Meervelt L - Acta Crystallogr Sect E Struct Rep Online (2014)

View of the crystal packing for the title compound, with (N/C)—H⋯Cl and C—H⋯O hydrogen bonds drawn as green and red dashed lines, respectively. [Symmetry codes: (i) x, −y + 1, z − ; (ii) −x + 1, y, −z + .]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120542&req=5

fig2: View of the crystal packing for the title compound, with (N/C)—H⋯Cl and C—H⋯O hydrogen bonds drawn as green and red dashed lines, respectively. [Symmetry codes: (i) x, −y + 1, z − ; (ii) −x + 1, y, −z + .]
Mentions: The crystal packing is characterized by N—H⋯Cl and C—H⋯O hydrogen bonds (Table 1 ▶). Mol­ecules are arranged into columns along the c axis (Fig. 2 ▶) with the piperidine rings all directed towards the center of the column, favouring hydro­phobic inter­actions.

Bottom Line: The title compound, [Pt(C10H6NO2)Cl(C5H11N)], crystallizes with one mol-ecule in the asymmetric unit.The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxyl-ate O atom of the bidentate quinaldate ligand and a piperidine N atom.In the crystal, mol-ecules are stacked into columns along the c axis by the formation of N-H⋯Cl and C-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, Hanoi National University of Education, 136 - Xuan Thuy - Cau Giay, Hanoi, Vietnam.

ABSTRACT
The title compound, [Pt(C10H6NO2)Cl(C5H11N)], crystallizes with one mol-ecule in the asymmetric unit. The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxyl-ate O atom of the bidentate quinaldate ligand and a piperidine N atom. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, mol-ecules are stacked into columns along the c axis by the formation of N-H⋯Cl and C-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus