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2,2,6,6-Tetra-bromo-3,4,4,5-tetra-meth-oxy-cyclo-hexa-none.

Faizi MS, Mashrai A, Shahid M - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title compound, C10H14Br4O5, synthesized from the meth-oxy Schiff base N-(pyridin-2-ylmeth-yl)meth-oxy-aniline and mol-ecular bromine, the cyclo-hexa-none ring has a chair conformation with one of the four meth-oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated.The C-Br bond lengthsvary from 1.942 (4) to1.964 (4) Å.Also present in the structure are two short inter-molecular Br⋯Ometh-oxy inter-actions [3.020 (3) and 3.073 (4) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India.

ABSTRACT
In the title compound, C10H14Br4O5, synthesized from the meth-oxy Schiff base N-(pyridin-2-ylmeth-yl)meth-oxy-aniline and mol-ecular bromine, the cyclo-hexa-none ring has a chair conformation with one of the four meth-oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated. The C-Br bond lengthsvary from 1.942 (4) to1.964 (4) Å. In the crystal, weak C-H⋯Ocarbon-yl hydrogen-bonding inter-actions generate chains extending along the b-axis direction. Also present in the structure are two short inter-molecular Br⋯Ometh-oxy inter-actions [3.020 (3) and 3.073 (4) Å].

No MeSH data available.


The one-dimensional hydrogen-bonded chain structure in the title compound extending along b, with hydrogen bonds shown as dashed lines.
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Fap2: The one-dimensional hydrogen-bonded chain structure in the title compound extending along b, with hydrogen bonds shown as dashed lines.


2,2,6,6-Tetra-bromo-3,4,4,5-tetra-meth-oxy-cyclo-hexa-none.

Faizi MS, Mashrai A, Shahid M - Acta Crystallogr Sect E Struct Rep Online (2014)

The one-dimensional hydrogen-bonded chain structure in the title compound extending along b, with hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120536&req=5

Fap2: The one-dimensional hydrogen-bonded chain structure in the title compound extending along b, with hydrogen bonds shown as dashed lines.
Bottom Line: In the title compound, C10H14Br4O5, synthesized from the meth-oxy Schiff base N-(pyridin-2-ylmeth-yl)meth-oxy-aniline and mol-ecular bromine, the cyclo-hexa-none ring has a chair conformation with one of the four meth-oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated.The C-Br bond lengthsvary from 1.942 (4) to1.964 (4) Å.Also present in the structure are two short inter-molecular Br⋯Ometh-oxy inter-actions [3.020 (3) and 3.073 (4) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India.

ABSTRACT
In the title compound, C10H14Br4O5, synthesized from the meth-oxy Schiff base N-(pyridin-2-ylmeth-yl)meth-oxy-aniline and mol-ecular bromine, the cyclo-hexa-none ring has a chair conformation with one of the four meth-oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated. The C-Br bond lengthsvary from 1.942 (4) to1.964 (4) Å. In the crystal, weak C-H⋯Ocarbon-yl hydrogen-bonding inter-actions generate chains extending along the b-axis direction. Also present in the structure are two short inter-molecular Br⋯Ometh-oxy inter-actions [3.020 (3) and 3.073 (4) Å].

No MeSH data available.