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μ2-Acetato-κ(2) O:O'-(4,4'-bipyridyl-κN)tris-(diethyl di-thio-phosphato-κ(2) S,S')-μ3-sulfido-tri-μ2-sulfido-trimolybdenum(IV) diethyl ether monosolvate.

Kawamoto K, Kinoshita I - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: If Mo-Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octa-hedral geometry.The Mo-Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo-Mo distances [2.7490 (5) and 2.7566 (5) Å].One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-Ku, Osaka 558-8585, Japan.

ABSTRACT
In the title compound, [Mo3(CH3COO)(C4H10O2PS2)3S4(C10H8N2)]·C4H10O, the complex mol-ecule has a trinuclear incomplete cuboidal structure which is coordinated by three kinds of ligands, namely, diethyl di-thio-phosphate, acetate and 4,4'-bipyridyl. If Mo-Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octa-hedral geometry. The Mo-Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo-Mo distances [2.7490 (5) and 2.7566 (5) Å]. One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio. In the crystal, weak C-H⋯O inter-actions link the trinuclear mol-ecules related by translation in [100] into chains. The crystal packing exhibits short inter-molecular S⋯S contacts of 3.1886 (13) Å. In other words, in this crystal packing, a supramolecular structure is constructed by the C-H⋯O and S⋯S interactions.

No MeSH data available.


The molecular structure of the title compound with the atom-labeling scheme (except of C and H atoms). Displacement elipsoids are drawn at the 50% probability level. Both components of the disordered ethyl group (attached to O3) are shown.
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Fap1: The molecular structure of the title compound with the atom-labeling scheme (except of C and H atoms). Displacement elipsoids are drawn at the 50% probability level. Both components of the disordered ethyl group (attached to O3) are shown.


μ2-Acetato-κ(2) O:O'-(4,4'-bipyridyl-κN)tris-(diethyl di-thio-phosphato-κ(2) S,S')-μ3-sulfido-tri-μ2-sulfido-trimolybdenum(IV) diethyl ether monosolvate.

Kawamoto K, Kinoshita I - Acta Crystallogr Sect E Struct Rep Online (2014)

The molecular structure of the title compound with the atom-labeling scheme (except of C and H atoms). Displacement elipsoids are drawn at the 50% probability level. Both components of the disordered ethyl group (attached to O3) are shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4120534&req=5

Fap1: The molecular structure of the title compound with the atom-labeling scheme (except of C and H atoms). Displacement elipsoids are drawn at the 50% probability level. Both components of the disordered ethyl group (attached to O3) are shown.
Bottom Line: If Mo-Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octa-hedral geometry.The Mo-Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo-Mo distances [2.7490 (5) and 2.7566 (5) Å].One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-Ku, Osaka 558-8585, Japan.

ABSTRACT
In the title compound, [Mo3(CH3COO)(C4H10O2PS2)3S4(C10H8N2)]·C4H10O, the complex mol-ecule has a trinuclear incomplete cuboidal structure which is coordinated by three kinds of ligands, namely, diethyl di-thio-phosphate, acetate and 4,4'-bipyridyl. If Mo-Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octa-hedral geometry. The Mo-Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo-Mo distances [2.7490 (5) and 2.7566 (5) Å]. One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio. In the crystal, weak C-H⋯O inter-actions link the trinuclear mol-ecules related by translation in [100] into chains. The crystal packing exhibits short inter-molecular S⋯S contacts of 3.1886 (13) Å. In other words, in this crystal packing, a supramolecular structure is constructed by the C-H⋯O and S⋯S interactions.

No MeSH data available.