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Acetonyltriphenyl-phospho-nium nitrate.

Diop T, Diop L, Kučeráková M, Dušek M - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°.The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character.C-H⋯O hydrogen bonds help to consolidate the crystal packing.

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Affiliation: Laboratoire de Chimie Minerale et Analytique, Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

ABSTRACT
Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing.

No MeSH data available.


The molecular entities of the title compound with displacement ellipsoids drawn at the 50% probability level.
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Fap1: The molecular entities of the title compound with displacement ellipsoids drawn at the 50% probability level.


Acetonyltriphenyl-phospho-nium nitrate.

Diop T, Diop L, Kučeráková M, Dušek M - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular entities of the title compound with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569822&req=5

Fap1: The molecular entities of the title compound with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°.The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character.C-H⋯O hydrogen bonds help to consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Minerale et Analytique, Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

ABSTRACT
Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing.

No MeSH data available.