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rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl-amide-borane hemihydrate.

Evans SJ, Renison CA, Williams DB, Muller A - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre.The crystal structure is assembled via O-H⋯O inter-actions between pairs of phosphininc amide mol-ecules and water molecules, creating hydrogen-bonded dimers with graph-set R(2) (4)(8) along [001].Weak C-H⋯O inter-actions are also observed.

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Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho-rus atoms shows distortions in their tetra-hedral environments with the cyclo-hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O-H⋯O inter-actions between pairs of phosphininc amide mol-ecules and water molecules, creating hydrogen-bonded dimers with graph-set R(2) (4)(8) along [001]. Weak C-H⋯O inter-actions are also observed.

No MeSH data available.


Related in: MedlinePlus

A view of the title complex, showing the atom-numbering scheme and 50% probability displacement ellipsoids. Hydrogen atoms (except for the water solvate) as well as the minor part of the disorder omitted for clarity.
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Fap1: A view of the title complex, showing the atom-numbering scheme and 50% probability displacement ellipsoids. Hydrogen atoms (except for the water solvate) as well as the minor part of the disorder omitted for clarity.


rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl-amide-borane hemihydrate.

Evans SJ, Renison CA, Williams DB, Muller A - Acta Crystallogr Sect E Struct Rep Online (2013)

A view of the title complex, showing the atom-numbering scheme and 50% probability displacement ellipsoids. Hydrogen atoms (except for the water solvate) as well as the minor part of the disorder omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569809&req=5

Fap1: A view of the title complex, showing the atom-numbering scheme and 50% probability displacement ellipsoids. Hydrogen atoms (except for the water solvate) as well as the minor part of the disorder omitted for clarity.
Bottom Line: In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre.The crystal structure is assembled via O-H⋯O inter-actions between pairs of phosphininc amide mol-ecules and water molecules, creating hydrogen-bonded dimers with graph-set R(2) (4)(8) along [001].Weak C-H⋯O inter-actions are also observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho-rus atoms shows distortions in their tetra-hedral environments with the cyclo-hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O-H⋯O inter-actions between pairs of phosphininc amide mol-ecules and water molecules, creating hydrogen-bonded dimers with graph-set R(2) (4)(8) along [001]. Weak C-H⋯O inter-actions are also observed.

No MeSH data available.


Related in: MedlinePlus