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(1S,3R,8R,9S,11R)-2,2,10,10-Tetra-chloro-3,7,7,11-tetra-methyl-tetra-cyclo-[6.5.0.0(1,3).0(9,11)]trideca-ne.

Ourhriss N, Benharref A, Saadi M, El Ammari L, Berraho M - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, C(17)H(24)Cl(4), was synthesized from β-himachalene (3,5,5,9-tetra-methyl-2,4a,5,6,7,8-hexa-hydro-1H-benzocyclo-heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica).The mol-ecule is built up from fused six- and seven-membered rings and two three-membered rings from the reaction of β-himachalene with dichloro-carbene.The six-membered ring shows a chair conformation, whereas the seven-membered ring displays a boat conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Biomoléculaire, Substances Naturelles et Réactivité "Unité Associée au CNRST(URAC16)", Faculté des Sciences Semlalia, BP 2390, Bd My Abdellah, 40000 Marrakech, Morocco.

ABSTRACT
The title compound, C(17)H(24)Cl(4), was synthesized from β-himachalene (3,5,5,9-tetra-methyl-2,4a,5,6,7,8-hexa-hydro-1H-benzocyclo-heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol-ecule is built up from fused six- and seven-membered rings and two three-membered rings from the reaction of β-himachalene with dichloro-carbene. The six-membered ring shows a chair conformation, whereas the seven-membered ring displays a boat conformation.

No MeSH data available.


Related in: MedlinePlus

: Molecular structure of the title compound with the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability. level. H atoms are represented as small spheres of arbitrary radii.
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Fap1: : Molecular structure of the title compound with the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability. level. H atoms are represented as small spheres of arbitrary radii.


(1S,3R,8R,9S,11R)-2,2,10,10-Tetra-chloro-3,7,7,11-tetra-methyl-tetra-cyclo-[6.5.0.0(1,3).0(9,11)]trideca-ne.

Ourhriss N, Benharref A, Saadi M, El Ammari L, Berraho M - Acta Crystallogr Sect E Struct Rep Online (2013)

: Molecular structure of the title compound with the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability. level. H atoms are represented as small spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569802&req=5

Fap1: : Molecular structure of the title compound with the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability. level. H atoms are represented as small spheres of arbitrary radii.
Bottom Line: The title compound, C(17)H(24)Cl(4), was synthesized from β-himachalene (3,5,5,9-tetra-methyl-2,4a,5,6,7,8-hexa-hydro-1H-benzocyclo-heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica).The mol-ecule is built up from fused six- and seven-membered rings and two three-membered rings from the reaction of β-himachalene with dichloro-carbene.The six-membered ring shows a chair conformation, whereas the seven-membered ring displays a boat conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Biomoléculaire, Substances Naturelles et Réactivité "Unité Associée au CNRST(URAC16)", Faculté des Sciences Semlalia, BP 2390, Bd My Abdellah, 40000 Marrakech, Morocco.

ABSTRACT
The title compound, C(17)H(24)Cl(4), was synthesized from β-himachalene (3,5,5,9-tetra-methyl-2,4a,5,6,7,8-hexa-hydro-1H-benzocyclo-heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol-ecule is built up from fused six- and seven-membered rings and two three-membered rings from the reaction of β-himachalene with dichloro-carbene. The six-membered ring shows a chair conformation, whereas the seven-membered ring displays a boat conformation.

No MeSH data available.


Related in: MedlinePlus