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3-Chloro-4-fluoro-anilinium picrate.

Sarojini BK, Narayana B, Yathirajan HS, Gerber T, van Brecht B, Betz R - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°].In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: P. A. College of Engineering, Department of Chemistry, Nadupadavu, Mangalore 574 153, India.

ABSTRACT
In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°]. In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers parallel to (001).

No MeSH data available.


Intermolecular contacts, viewed along [-1 0 0]. For reasons of clarity, only a selection of intermolecular contacts is shown. Blue dashed lines depict classical hydrogen bonds of the N–H···O type, green dashed lines depict C–H···O contacts. Symmetry operator: i -x + 1, -y + 2, -z.
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Fap2: Intermolecular contacts, viewed along [-1 0 0]. For reasons of clarity, only a selection of intermolecular contacts is shown. Blue dashed lines depict classical hydrogen bonds of the N–H···O type, green dashed lines depict C–H···O contacts. Symmetry operator: i -x + 1, -y + 2, -z.


3-Chloro-4-fluoro-anilinium picrate.

Sarojini BK, Narayana B, Yathirajan HS, Gerber T, van Brecht B, Betz R - Acta Crystallogr Sect E Struct Rep Online (2013)

Intermolecular contacts, viewed along [-1 0 0]. For reasons of clarity, only a selection of intermolecular contacts is shown. Blue dashed lines depict classical hydrogen bonds of the N–H···O type, green dashed lines depict C–H···O contacts. Symmetry operator: i -x + 1, -y + 2, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569773&req=5

Fap2: Intermolecular contacts, viewed along [-1 0 0]. For reasons of clarity, only a selection of intermolecular contacts is shown. Blue dashed lines depict classical hydrogen bonds of the N–H···O type, green dashed lines depict C–H···O contacts. Symmetry operator: i -x + 1, -y + 2, -z.
Bottom Line: In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°].In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: P. A. College of Engineering, Department of Chemistry, Nadupadavu, Mangalore 574 153, India.

ABSTRACT
In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°]. In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers parallel to (001).

No MeSH data available.