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[(1R,3S)-2,2-Dichloro-3-(hy-droxy-meth-yl)cyclo-prop-yl]methanol.

Kailani MH - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol-ecules per asymmetric unit.The mol-ecules form helical associates with a pitch of 6.31 Å along the a axis via O-H⋯O hydrogen bonds.The overall three-dimesional supra-molecular architecture is stabilized by C-Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C-Cl⋯O angle of 162.5 (2)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, The University of Jordan, Amman 11942, Jordan.

ABSTRACT
The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol-ecules per asymmetric unit. The mol-ecules form helical associates with a pitch of 6.31 Å along the a axis via O-H⋯O hydrogen bonds. The overall three-dimesional supra-molecular architecture is stabilized by C-Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C-Cl⋯O angle of 162.5 (2)°.

No MeSH data available.


Related in: MedlinePlus

Left-handed hydrogen-bonded helix (oxygens are in red and hydrogens - in blue), running along a-axis with supporting halogen bonding interactions, shown as black dotted lines.
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Fap2: Left-handed hydrogen-bonded helix (oxygens are in red and hydrogens - in blue), running along a-axis with supporting halogen bonding interactions, shown as black dotted lines.


[(1R,3S)-2,2-Dichloro-3-(hy-droxy-meth-yl)cyclo-prop-yl]methanol.

Kailani MH - Acta Crystallogr Sect E Struct Rep Online (2013)

Left-handed hydrogen-bonded helix (oxygens are in red and hydrogens - in blue), running along a-axis with supporting halogen bonding interactions, shown as black dotted lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569760&req=5

Fap2: Left-handed hydrogen-bonded helix (oxygens are in red and hydrogens - in blue), running along a-axis with supporting halogen bonding interactions, shown as black dotted lines.
Bottom Line: The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol-ecules per asymmetric unit.The mol-ecules form helical associates with a pitch of 6.31 Å along the a axis via O-H⋯O hydrogen bonds.The overall three-dimesional supra-molecular architecture is stabilized by C-Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C-Cl⋯O angle of 162.5 (2)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, The University of Jordan, Amman 11942, Jordan.

ABSTRACT
The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol-ecules per asymmetric unit. The mol-ecules form helical associates with a pitch of 6.31 Å along the a axis via O-H⋯O hydrogen bonds. The overall three-dimesional supra-molecular architecture is stabilized by C-Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C-Cl⋯O angle of 162.5 (2)°.

No MeSH data available.


Related in: MedlinePlus