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2,4,6,8-Tetra-kis(2-fluoro-phen-yl)-3,7-diaza-bicyclo-[3.3.1]nonan-9-one.

Park DH, Ramkumar V, Parthiban P - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, C(31)H(24)F(4)N(2)O, exists in a chair-boat conformation with an equatorial orientation of the 2-fluoro-phenyl groups on both sides of the secondary amino group of the chair form.The benzene rings in the 'chair' part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the 'boat' part is 75.6 (1)°.One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biomedicinal Chemistry, Inje University, Gimhae, Gyeongnam 621 749, Republic of Korea.

ABSTRACT
The title compound, C(31)H(24)F(4)N(2)O, exists in a chair-boat conformation with an equatorial orientation of the 2-fluoro-phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the 'chair' part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the 'boat' part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains along [001] and these chains are held together via weak N-H⋯F and C-H⋯F inter-actions.

No MeSH data available.


View of (I) showing the atomic numbering and 30% probability displacement ellipsoids. For the disordered atoms, only major part is shown.
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Fap1: View of (I) showing the atomic numbering and 30% probability displacement ellipsoids. For the disordered atoms, only major part is shown.


2,4,6,8-Tetra-kis(2-fluoro-phen-yl)-3,7-diaza-bicyclo-[3.3.1]nonan-9-one.

Park DH, Ramkumar V, Parthiban P - Acta Crystallogr Sect E Struct Rep Online (2013)

View of (I) showing the atomic numbering and 30% probability displacement ellipsoids. For the disordered atoms, only major part is shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569241&req=5

Fap1: View of (I) showing the atomic numbering and 30% probability displacement ellipsoids. For the disordered atoms, only major part is shown.
Bottom Line: The title compound, C(31)H(24)F(4)N(2)O, exists in a chair-boat conformation with an equatorial orientation of the 2-fluoro-phenyl groups on both sides of the secondary amino group of the chair form.The benzene rings in the 'chair' part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the 'boat' part is 75.6 (1)°.One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biomedicinal Chemistry, Inje University, Gimhae, Gyeongnam 621 749, Republic of Korea.

ABSTRACT
The title compound, C(31)H(24)F(4)N(2)O, exists in a chair-boat conformation with an equatorial orientation of the 2-fluoro-phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the 'chair' part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the 'boat' part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains along [001] and these chains are held together via weak N-H⋯F and C-H⋯F inter-actions.

No MeSH data available.