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Bis(2-amino-4-methyl-pyrimidin-1-ium) hexa-aqua-cobalt(II) disulfate dihydrate.

Mirzaei M, Eshtiagh-Hosseini H, Zarghami S, Karrabi Z, Saeedi M, Mague JT - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa-hedral hexa-aqua complex cation is generated by crystallographic inversion symmetry.In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R(2) (2)(8) loops.These, together with π-π inter-actions between centrosymmetrically related pyrimidinium cations [centroid-centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Ferdowsi University of Mashhad, 917751436 Mashhad, Iran.

ABSTRACT
In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa-hedral hexa-aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R(2) (2)(8) loops. These, together with π-π inter-actions between centrosymmetrically related pyrimidinium cations [centroid-centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

N—H···O hydrogen bonds and the R22(8) synthons (N2, N3, O5 O6).
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Fap3: N—H···O hydrogen bonds and the R22(8) synthons (N2, N3, O5 O6).


Bis(2-amino-4-methyl-pyrimidin-1-ium) hexa-aqua-cobalt(II) disulfate dihydrate.

Mirzaei M, Eshtiagh-Hosseini H, Zarghami S, Karrabi Z, Saeedi M, Mague JT - Acta Crystallogr Sect E Struct Rep Online (2013)

N—H···O hydrogen bonds and the R22(8) synthons (N2, N3, O5 O6).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569216&req=5

Fap3: N—H···O hydrogen bonds and the R22(8) synthons (N2, N3, O5 O6).
Bottom Line: In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa-hedral hexa-aqua complex cation is generated by crystallographic inversion symmetry.In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R(2) (2)(8) loops.These, together with π-π inter-actions between centrosymmetrically related pyrimidinium cations [centroid-centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Ferdowsi University of Mashhad, 917751436 Mashhad, Iran.

ABSTRACT
In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa-hedral hexa-aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R(2) (2)(8) loops. These, together with π-π inter-actions between centrosymmetrically related pyrimidinium cations [centroid-centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus