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μ-Oxalato-bis-[bis-(triphenyl-phosphine)copper(I)] dichloro-methane disolvate.

Royappa AD, Golen JA, Rheingold AL, Royappa AT - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms.Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°].In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of West Florida, 11000 University Parkway, Pensacola, FL 32514, USA.

ABSTRACT
The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

No MeSH data available.


The molecular structure of the title compound showing displacement ellipsoids at the 30% probability level. Neither the H atoms nor the solvent molecules are shown (Symmetry code: (a) -x, -y+1, -z+1).
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Fap1: The molecular structure of the title compound showing displacement ellipsoids at the 30% probability level. Neither the H atoms nor the solvent molecules are shown (Symmetry code: (a) -x, -y+1, -z+1).


μ-Oxalato-bis-[bis-(triphenyl-phosphine)copper(I)] dichloro-methane disolvate.

Royappa AD, Golen JA, Rheingold AL, Royappa AT - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular structure of the title compound showing displacement ellipsoids at the 30% probability level. Neither the H atoms nor the solvent molecules are shown (Symmetry code: (a) -x, -y+1, -z+1).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569214&req=5

Fap1: The molecular structure of the title compound showing displacement ellipsoids at the 30% probability level. Neither the H atoms nor the solvent molecules are shown (Symmetry code: (a) -x, -y+1, -z+1).
Bottom Line: The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms.Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°].In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of West Florida, 11000 University Parkway, Pensacola, FL 32514, USA.

ABSTRACT
The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

No MeSH data available.