Limits...
Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ato-κO)tetra-kis-(methanol-κO)calcium methanol tetra-solvate.

Kim N, Noh H, Yoon S, Park CR - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa-coordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa-hedral coordination geometry.The Ca-O-C angle between the carboxyl-ate group and the calcium ion is 171.8 (2)°.Two types of inter-molecular hydrogen-bond inter-actions (C=O⋯H and O-H⋯O) between the carboxyl-ate ligand, the methanol solvent mol-ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Bio & Nano Chemistry, College of Natural Sciences, Kookmin University, 861-1 Jeongneung-dong, Seongbuk-gu, Seoul 136-702, Republic of Korea.

ABSTRACT
In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa-coordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa-hedral coordination geometry. The Ca-O-C angle between the carboxyl-ate group and the calcium ion is 171.8 (2)°. Two types of inter-molecular hydrogen-bond inter-actions (C=O⋯H and O-H⋯O) between the carboxyl-ate ligand, the methanol solvent mol-ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound, showing the atom-numbering and with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3569211&req=5

Fap1: The molecular structure of the title compound, showing the atom-numbering and with displacement ellipsoids drawn at the 50% probability level.


Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ato-κO)tetra-kis-(methanol-κO)calcium methanol tetra-solvate.

Kim N, Noh H, Yoon S, Park CR - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular structure of the title compound, showing the atom-numbering and with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569211&req=5

Fap1: The molecular structure of the title compound, showing the atom-numbering and with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa-coordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa-hedral coordination geometry.The Ca-O-C angle between the carboxyl-ate group and the calcium ion is 171.8 (2)°.Two types of inter-molecular hydrogen-bond inter-actions (C=O⋯H and O-H⋯O) between the carboxyl-ate ligand, the methanol solvent mol-ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Bio & Nano Chemistry, College of Natural Sciences, Kookmin University, 861-1 Jeongneung-dong, Seongbuk-gu, Seoul 136-702, Republic of Korea.

ABSTRACT
In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa-coordinated by two O atoms of two 4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa-hedral coordination geometry. The Ca-O-C angle between the carboxyl-ate group and the calcium ion is 171.8 (2)°. Two types of inter-molecular hydrogen-bond inter-actions (C=O⋯H and O-H⋯O) between the carboxyl-ate ligand, the methanol solvent mol-ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).

No MeSH data available.


Related in: MedlinePlus