Limits...
{Bis[N,N'-dicyclo-hexyl-N'',N''-bis-(tri-meth-yl-sil-yl)guanidinato-κ(2)N,N']neo-dymium(III)}di-μ-chlorido-[bis-(tetra-hydro-furan-κO)lithium].

Chi SH, Chen J - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo-hex-yl) and Li(THF)(2) (+) units (THF is tetra-hydro-furan) are connected by two bridging Cl atoms.The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa-hedral geometry.The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol-ecules in a distorted tetra-hedral geometry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, People's Republic of China ; Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China.

ABSTRACT
In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo-hex-yl) and Li(THF)(2) (+) units (THF is tetra-hydro-furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa-hedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol-ecules in a distorted tetra-hedral geometry.

No MeSH data available.


Molecular structure of the title compound with displacement elliposids drawn at the 10% probability level. Atoms with suffix A are generated by the symmetry operation (1 - x, 1 - y, 1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3569210&req=5

Fap1: Molecular structure of the title compound with displacement elliposids drawn at the 10% probability level. Atoms with suffix A are generated by the symmetry operation (1 - x, 1 - y, 1 - z).


{Bis[N,N'-dicyclo-hexyl-N'',N''-bis-(tri-meth-yl-sil-yl)guanidinato-κ(2)N,N']neo-dymium(III)}di-μ-chlorido-[bis-(tetra-hydro-furan-κO)lithium].

Chi SH, Chen J - Acta Crystallogr Sect E Struct Rep Online (2013)

Molecular structure of the title compound with displacement elliposids drawn at the 10% probability level. Atoms with suffix A are generated by the symmetry operation (1 - x, 1 - y, 1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569210&req=5

Fap1: Molecular structure of the title compound with displacement elliposids drawn at the 10% probability level. Atoms with suffix A are generated by the symmetry operation (1 - x, 1 - y, 1 - z).
Bottom Line: In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo-hex-yl) and Li(THF)(2) (+) units (THF is tetra-hydro-furan) are connected by two bridging Cl atoms.The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa-hedral geometry.The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol-ecules in a distorted tetra-hedral geometry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, People's Republic of China ; Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China.

ABSTRACT
In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo-hex-yl) and Li(THF)(2) (+) units (THF is tetra-hydro-furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa-hedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol-ecules in a distorted tetra-hedral geometry.

No MeSH data available.