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cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II).

Eliseev II, Bokach NA, Haukka M, Golenya IA - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry.The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes.The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H⋯O hydrogen bond.

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Affiliation: Department of Chemistry, St Petersburg State University, 198504 Petrodvorets, Russian Federation.

ABSTRACT
In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H⋯O hydrogen bond.

No MeSH data available.


Molecular structure of (I), showing the atom-numbering scheme with displacement ellipsoids drawn at the 50% probability level.
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Fap1: Molecular structure of (I), showing the atom-numbering scheme with displacement ellipsoids drawn at the 50% probability level.


cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II).

Eliseev II, Bokach NA, Haukka M, Golenya IA - Acta Crystallogr Sect E Struct Rep Online (2013)

Molecular structure of (I), showing the atom-numbering scheme with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569208&req=5

Fap1: Molecular structure of (I), showing the atom-numbering scheme with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry.The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes.The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H⋯O hydrogen bond.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, St Petersburg State University, 198504 Petrodvorets, Russian Federation.

ABSTRACT
In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H⋯O hydrogen bond.

No MeSH data available.