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Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')mercury(II).

Warad I, Al-Noaimi M, Haddad SF, Othman R - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra-hedral environment.The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å).The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, AN-Najah National University, Nablus, Palestinian Territories.

ABSTRACT
The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra-hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.

No MeSH data available.


An ORTEP (Burnett & Johnson, 1996) view of Hg(Cl)2(dmphen). Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
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Fap1: An ORTEP (Burnett & Johnson, 1996) view of Hg(Cl)2(dmphen). Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.


Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')mercury(II).

Warad I, Al-Noaimi M, Haddad SF, Othman R - Acta Crystallogr Sect E Struct Rep Online (2013)

An ORTEP (Burnett & Johnson, 1996) view of Hg(Cl)2(dmphen). Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569203&req=5

Fap1: An ORTEP (Burnett & Johnson, 1996) view of Hg(Cl)2(dmphen). Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
Bottom Line: The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra-hedral environment.The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å).The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, AN-Najah National University, Nablus, Palestinian Territories.

ABSTRACT
The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra-hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.

No MeSH data available.