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Tetra-methyl-ammonium aqua-trichlorido-oxalatostannate(IV) monohydrate.

Sow Y, Diop L, Molloy KC, Kociok-Köhn G - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion.The environment around the Sn(IV) atom is distorted octa-hedral.The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H⋯O and C-H⋯Cl inter-actions.

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Affiliation: Laboratoire de Chimie Minerale et Analytique (LACHIMIA), Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

ABSTRACT
The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa-hedral. The anions are connected by the lattice water mol-ecule through O-H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H⋯O and C-H⋯Cl inter-actions.

No MeSH data available.


The asymmetric unit showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: The asymmetric unit showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.


Tetra-methyl-ammonium aqua-trichlorido-oxalatostannate(IV) monohydrate.

Sow Y, Diop L, Molloy KC, Kociok-Köhn G - Acta Crystallogr Sect E Struct Rep Online (2013)

The asymmetric unit showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569201&req=5

Fap1: The asymmetric unit showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion.The environment around the Sn(IV) atom is distorted octa-hedral.The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H⋯O and C-H⋯Cl inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Minerale et Analytique (LACHIMIA), Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.

ABSTRACT
The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa-hedral. The anions are connected by the lattice water mol-ecule through O-H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H⋯O and C-H⋯Cl inter-actions.

No MeSH data available.