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Bis[μ-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-cobalt(II)].

Wang L - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center.The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand.In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.

ABSTRACT
The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

No MeSH data available.


The molecular structure with displacement ellipsoids drawn at the 30% probability level, hydrogen atoms are omited for clarity [Symmetry code (a): -x+3, -y, -z+1].
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Fap1: The molecular structure with displacement ellipsoids drawn at the 30% probability level, hydrogen atoms are omited for clarity [Symmetry code (a): -x+3, -y, -z+1].


Bis[μ-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-cobalt(II)].

Wang L - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular structure with displacement ellipsoids drawn at the 30% probability level, hydrogen atoms are omited for clarity [Symmetry code (a): -x+3, -y, -z+1].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569198&req=5

Fap1: The molecular structure with displacement ellipsoids drawn at the 30% probability level, hydrogen atoms are omited for clarity [Symmetry code (a): -x+3, -y, -z+1].
Bottom Line: The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center.The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand.In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.

ABSTRACT
The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

No MeSH data available.