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Bis{2-[(2,4,6-trimethyl-phen-yl)imino-methyl]pyrrol-1-ido}palladium(II).

Imhof W - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom.In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers.The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: University Koblenz-Landau, Institute for Integrated Natural Sciences, Universitätsstrasse 1, 56070 Koblenz, Germany.

ABSTRACT
The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.

No MeSH data available.


Molecular structure of the molecule with Pd2 being situated at a inversion center with thermal ellipsoids at the 50% probability level (i = -x, -1 - y, -z).
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Fap2: Molecular structure of the molecule with Pd2 being situated at a inversion center with thermal ellipsoids at the 50% probability level (i = -x, -1 - y, -z).


Bis{2-[(2,4,6-trimethyl-phen-yl)imino-methyl]pyrrol-1-ido}palladium(II).

Imhof W - Acta Crystallogr Sect E Struct Rep Online (2013)

Molecular structure of the molecule with Pd2 being situated at a inversion center with thermal ellipsoids at the 50% probability level (i = -x, -1 - y, -z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569194&req=5

Fap2: Molecular structure of the molecule with Pd2 being situated at a inversion center with thermal ellipsoids at the 50% probability level (i = -x, -1 - y, -z).
Bottom Line: The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom.In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers.The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: University Koblenz-Landau, Institute for Integrated Natural Sciences, Universitätsstrasse 1, 56070 Koblenz, Germany.

ABSTRACT
The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.

No MeSH data available.