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Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κ(2)N(3),O)cobalt(II).

Artetxe B, San Felices L, Pache A, Reinoso S, Gutiérrez-Zorrilla JM - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa-hedral coordination geometry.The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are occupied by water mol-ecules.The crystal packing consists of a three-dimensional network stabilized by O-H⋯O and N-H⋯O hydrogen bonds, together with weak π-π inter-actions [centroid-centroid distance = 3.577 (2) Å] between the imidazole rings.

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Affiliation: Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad de País Vasco, UPV/EHU, PO Box 644, E-48080 Bilbao, Spain.

ABSTRACT
The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa-hedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are occupied by water mol-ecules. The crystal packing consists of a three-dimensional network stabilized by O-H⋯O and N-H⋯O hydrogen bonds, together with weak π-π inter-actions [centroid-centroid distance = 3.577 (2) Å] between the imidazole rings.

No MeSH data available.


Related in: MedlinePlus

View of the crystal packing along the crystallographic a axis (hydrogen bonds represented as dashed lines).
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Fap2: View of the crystal packing along the crystallographic a axis (hydrogen bonds represented as dashed lines).


Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κ(2)N(3),O)cobalt(II).

Artetxe B, San Felices L, Pache A, Reinoso S, Gutiérrez-Zorrilla JM - Acta Crystallogr Sect E Struct Rep Online (2013)

View of the crystal packing along the crystallographic a axis (hydrogen bonds represented as dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569192&req=5

Fap2: View of the crystal packing along the crystallographic a axis (hydrogen bonds represented as dashed lines).
Bottom Line: The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa-hedral coordination geometry.The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are occupied by water mol-ecules.The crystal packing consists of a three-dimensional network stabilized by O-H⋯O and N-H⋯O hydrogen bonds, together with weak π-π inter-actions [centroid-centroid distance = 3.577 (2) Å] between the imidazole rings.

View Article: PubMed Central - HTML - PubMed

Affiliation: Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad de País Vasco, UPV/EHU, PO Box 644, E-48080 Bilbao, Spain.

ABSTRACT
The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa-hedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands and the axial positions are occupied by water mol-ecules. The crystal packing consists of a three-dimensional network stabilized by O-H⋯O and N-H⋯O hydrogen bonds, together with weak π-π inter-actions [centroid-centroid distance = 3.577 (2) Å] between the imidazole rings.

No MeSH data available.


Related in: MedlinePlus