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Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa-phenyl-tetra-tin(IV) dimethyl sulfoxide disolvate.

Foladi S, Khazaei P, Attar Gharamaleki J, Notash B, Rofouei MK - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries.The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares.The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Karaj Branch, Islamic Azad, University, Karaj, Iran.

ABSTRACT
In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H⋯O hydrogen bonds.

No MeSH data available.


View of (I) showing the atomic numbering and 50% probability displacement ellipsoids [symmetry code: (a) 2-x, -y, 2-z]. Solvent molecule and C-bound H atoms were omitted for clarity.
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Fap1: View of (I) showing the atomic numbering and 50% probability displacement ellipsoids [symmetry code: (a) 2-x, -y, 2-z]. Solvent molecule and C-bound H atoms were omitted for clarity.


Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa-phenyl-tetra-tin(IV) dimethyl sulfoxide disolvate.

Foladi S, Khazaei P, Attar Gharamaleki J, Notash B, Rofouei MK - Acta Crystallogr Sect E Struct Rep Online (2013)

View of (I) showing the atomic numbering and 50% probability displacement ellipsoids [symmetry code: (a) 2-x, -y, 2-z]. Solvent molecule and C-bound H atoms were omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569190&req=5

Fap1: View of (I) showing the atomic numbering and 50% probability displacement ellipsoids [symmetry code: (a) 2-x, -y, 2-z]. Solvent molecule and C-bound H atoms were omitted for clarity.
Bottom Line: In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries.The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares.The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Karaj Branch, Islamic Azad, University, Karaj, Iran.

ABSTRACT
In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H⋯O hydrogen bonds.

No MeSH data available.