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Di-μ-chlorido-bis-{[2-(di-tert-butyl-phosphan-yl)biphenyl-3-yl-κ(2)C(3),P]palladium(II)} dichloro-methane disolvate.

Holzapfel CW, Omondi B - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring.The Pd(2)Cl(2) unit is located about an inversion center.The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.

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Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, Auckland Park Kingsway Campus, PO Box 524, Auckland Park 2006, South Africa.

ABSTRACT
The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol-ecule of the palladium complex and a dichloro-methane solvent mol-ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.

No MeSH data available.


The molecular structure and atom-numbering scheme for (I), with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omited for clarity. The assymetric unit only has only half a molecule of the palladium complex, the other half generated by the symetry operator -x, -y, -z.
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Fap1: The molecular structure and atom-numbering scheme for (I), with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omited for clarity. The assymetric unit only has only half a molecule of the palladium complex, the other half generated by the symetry operator -x, -y, -z.


Di-μ-chlorido-bis-{[2-(di-tert-butyl-phosphan-yl)biphenyl-3-yl-κ(2)C(3),P]palladium(II)} dichloro-methane disolvate.

Holzapfel CW, Omondi B - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular structure and atom-numbering scheme for (I), with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omited for clarity. The assymetric unit only has only half a molecule of the palladium complex, the other half generated by the symetry operator -x, -y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569185&req=5

Fap1: The molecular structure and atom-numbering scheme for (I), with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omited for clarity. The assymetric unit only has only half a molecule of the palladium complex, the other half generated by the symetry operator -x, -y, -z.
Bottom Line: In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring.The Pd(2)Cl(2) unit is located about an inversion center.The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, Auckland Park Kingsway Campus, PO Box 524, Auckland Park 2006, South Africa.

ABSTRACT
The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol-ecule of the palladium complex and a dichloro-methane solvent mol-ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.

No MeSH data available.