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Poly[bis-(μ(2)-5-{4-[(1H-imidazol-1-yl)meth-yl]phen-yl}tetra-zolato)zinc].

Song Z - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry.The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010).The structure is further stabilized by C-H⋯N, C-H⋯π and π-π [centroid-centroid distance = 3.7523 (11) Å] inter-actions within the network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Changchun Normal University, Changchun 130032, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C-H⋯N, C-H⋯π and π-π [centroid-centroid distance = 3.7523 (11) Å] inter-actions within the network.

No MeSH data available.


Related in: MedlinePlus

The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. Symmetry codes: (i) -x+1, y, -z+3/2; (ii) -x+3/2, -y-1/2, z+1/2; (iii) x-1/2, -y-1/2, -z+1.
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Fap1: The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. Symmetry codes: (i) -x+1, y, -z+3/2; (ii) -x+3/2, -y-1/2, z+1/2; (iii) x-1/2, -y-1/2, -z+1.


Poly[bis-(μ(2)-5-{4-[(1H-imidazol-1-yl)meth-yl]phen-yl}tetra-zolato)zinc].

Song Z - Acta Crystallogr Sect E Struct Rep Online (2013)

The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. Symmetry codes: (i) -x+1, y, -z+3/2; (ii) -x+3/2, -y-1/2, z+1/2; (iii) x-1/2, -y-1/2, -z+1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569184&req=5

Fap1: The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. Symmetry codes: (i) -x+1, y, -z+3/2; (ii) -x+3/2, -y-1/2, z+1/2; (iii) x-1/2, -y-1/2, -z+1.
Bottom Line: In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry.The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010).The structure is further stabilized by C-H⋯N, C-H⋯π and π-π [centroid-centroid distance = 3.7523 (11) Å] inter-actions within the network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Changchun Normal University, Changchun 130032, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C-H⋯N, C-H⋯π and π-π [centroid-centroid distance = 3.7523 (11) Å] inter-actions within the network.

No MeSH data available.


Related in: MedlinePlus