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Di-渭-thio-semicarbazide-魏(4)S:S-bis-[chlori-dobis(triphenyl-phosphane-魏P)silver(I)].

Wattanakanjana Y, Pakawatchai C, Nimthong R - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: The dinuclear title complex, [Ag(2)Cl(2)(CH(5)N(3)S)(2)(C(18)H(15)P)(2)], lies across an inversion center.The Ag(I) ion exhibits a slightly distorted tetra-hedral coordination geometry formed by a P atom from a triphenyl-phosphane ligand, two metal-bridging S atoms from thio-semicabazide ligands and one chloride ion.These layers are connected through π-π stacking inter-actions [centroid-centroid distance = 3.665鈥(2)鈥Å], leading to the formation of a three-dimensional network.

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Affiliation: Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.

ABSTRACT
The dinuclear title complex, [Ag(2)Cl(2)(CH(5)N(3)S)(2)(C(18)H(15)P)(2)], lies across an inversion center. The Ag(I) ion exhibits a slightly distorted tetra-hedral coordination geometry formed by a P atom from a triphenyl-phosphane ligand, two metal-bridging S atoms from thio-semicabazide ligands and one chloride ion. The S atoms bridge two symmetry-related Ag(I) ions, forming a strictly planar Ag(2)S(2) core with an Ag鈰疉g separation of 2.7802鈥(7)鈥吤. There is an intra-molecular N-H鈰疌l hydrogen bond. In the crystal, N-H鈰疌l and N-H鈰疭 hydrogen bonds link complex mol-ecules, forming layers parallel to (001). These layers are connected through 蟺-蟺 stacking inter-actions [centroid-centroid distance = 3.665鈥(2)鈥吤匽, leading to the formation of a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

Part of the crystal structure with N鈥擧路路路S and N鈥擧路路路Cl hydrogen bonds shown as dashed lines.
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Fap2: Part of the crystal structure with N鈥擧路路路S and N鈥擧路路路Cl hydrogen bonds shown as dashed lines.


Di-渭-thio-semicarbazide-魏(4)S:S-bis-[chlori-dobis(triphenyl-phosphane-魏P)silver(I)].

Wattanakanjana Y, Pakawatchai C, Nimthong R - Acta Crystallogr Sect E Struct Rep Online (2013)

Part of the crystal structure with N鈥擧路路路S and N鈥擧路路路Cl hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569183&req=5

Fap2: Part of the crystal structure with N鈥擧路路路S and N鈥擧路路路Cl hydrogen bonds shown as dashed lines.
Bottom Line: The dinuclear title complex, [Ag(2)Cl(2)(CH(5)N(3)S)(2)(C(18)H(15)P)(2)], lies across an inversion center.The Ag(I) ion exhibits a slightly distorted tetra-hedral coordination geometry formed by a P atom from a triphenyl-phosphane ligand, two metal-bridging S atoms from thio-semicabazide ligands and one chloride ion.These layers are connected through π-π stacking inter-actions [centroid-centroid distance = 3.665鈥(2)鈥Å], leading to the formation of a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.

ABSTRACT
The dinuclear title complex, [Ag(2)Cl(2)(CH(5)N(3)S)(2)(C(18)H(15)P)(2)], lies across an inversion center. The Ag(I) ion exhibits a slightly distorted tetra-hedral coordination geometry formed by a P atom from a triphenyl-phosphane ligand, two metal-bridging S atoms from thio-semicabazide ligands and one chloride ion. The S atoms bridge two symmetry-related Ag(I) ions, forming a strictly planar Ag(2)S(2) core with an Ag鈰疉g separation of 2.7802鈥(7)鈥吤. There is an intra-molecular N-H鈰疌l hydrogen bond. In the crystal, N-H鈰疌l and N-H鈰疭 hydrogen bonds link complex mol-ecules, forming layers parallel to (001). These layers are connected through 蟺-蟺 stacking inter-actions [centroid-centroid distance = 3.665鈥(2)鈥吤匽, leading to the formation of a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus