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Bis(diethyl-amido-κN)(diethyl-amine-κN)bis-(2,6-diisopropyl-phenyl-amido-κN)zirconium(IV).

Zauliczny M, Grubba R, Ponikiewski L, Pikies J - Acta Crystallogr Sect E Struct Rep Online (2013)

Bottom Line: In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal-bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions.An intra-molecular N-H⋯N contact occurs.There are two independent molecules in the asymmetric unit.

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Affiliation: Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland.

ABSTRACT
In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal-bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra-molecular N-H⋯N contact occurs. There are two independent molecules in the asymmetric unit.

No MeSH data available.


The molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at the 30% probability level H atoms connected to C have been omitted.
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Fap1: The molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at the 30% probability level H atoms connected to C have been omitted.


Bis(diethyl-amido-κN)(diethyl-amine-κN)bis-(2,6-diisopropyl-phenyl-amido-κN)zirconium(IV).

Zauliczny M, Grubba R, Ponikiewski L, Pikies J - Acta Crystallogr Sect E Struct Rep Online (2013)

The molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at the 30% probability level H atoms connected to C have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3569177&req=5

Fap1: The molecular structure of the title molecule with the atom-numbering. Displacement ellipsoids are drawn at the 30% probability level H atoms connected to C have been omitted.
Bottom Line: In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal-bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions.An intra-molecular N-H⋯N contact occurs.There are two independent molecules in the asymmetric unit.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemical Faculty, Gdansk University of Technology, Gabriela Narutowicza Street 11/12, 80-233 Gdansk, Poland.

ABSTRACT
In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal-bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra-molecular N-H⋯N contact occurs. There are two independent molecules in the asymmetric unit.

No MeSH data available.